OK, so to answer this question, you will simply use the molality equation which is as follows:
<span>M1V1 = M2V2
In the givens you have:
M1 = 2M
V1 is the unknown
M2 = 0.4M
V2 = 100 ml
</span>plug in the givens in the above equation:
<span>2 x V1 = 0.4 x 100
</span>therefore:
V1 = 20 ml
Based on this: you should take 20 ml of the 2 M solution and make volume exactly 100 ml in a volumetric flask by diluting in water.
Given information : Sample of 
We need to find the moles of Chlorine in the given sample.
We can say that we need to find moles from the given atoms.
Relation between mole and atom is given by : 
Where
is Avogadro number.


On solving the above equation , atoms(unit) gets cancelled out and we get 0.0286 mol.
In the given sample the moles of Chlorine (Cl) is 0.0286 mol , so option A is correct.
The moles which were measured out is calculated using the following formula
moles = mass/molar mass
molar mass of CuBr2.4H20 = 63.5 Cu + ( 2 x79.9) br + ( 18 x4_) h20 = 295.3 g/mol
moles is therefore= 5.2 g/ 295.3 g/mol= 0.0176 moles