(Thermodynamics)
1 answer:
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Answer:
See explanation and images attached
Explanation:
a) In the mechanism for the acid catalysed esterification of propanoic acid using ethanol, we can see that the first step is the protonation of the acid followed by nucleophillic attack of the alcohol. Loss of water and consequent deprotonation regenerates the acid catalyst. We can see the fate of the 18O labelled ethanol in the mechanism shown.
b) In the second mechanism, an unnamed ester is hydrolysed using an acid catalyst. The attack of the acid and subsequent nucleophillic attack of water labelled with 18O leads to the incorporation of this 18O into the product acid as shown in the mechanism attached to this answer.
Answer:
Explanation:
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In this case, given this is an acid-base neutralization and we are considering a diprotic acid, we can write the following mole-mole relationship:
It means that the moles of acid can be computed given the volume and concentration of NaOH:
It means that the approximate molar mass of the acid is:
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86.66 % by weight of ascorbic acid in the tablet, when 0. 1220 g vitamin c tablet was dissolved in acid. This required 11. 50 ml of 0. 01740 m to reach the endpoint.
A balanced chemical reaction is an equation that has equal numbers of each type of atom on both sides of the arrow.
→
So, the balanced chemical equation for the reaction will be:
→
That means, 3 mol of of ascorbic acid reacts with 1 mol of
Moles of available is 0.0174 X 0.0115 =0.0002001 mol
Moles of ascorbic acid to be yielded should be 3 X 0.0002001 =0.0006003
So, percent mass of ascorbic acid in the tablet will be:
(0.1057 / 0.1220) X 100 %
=86.66 %
Hence, the third option is the correct answer.
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