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nadya68 [22]
3 years ago
13

Which of the following statements is true concerning an aqueous solution of the weak base NH3?

Chemistry
1 answer:
babunello [35]3 years ago
8 0

Answer: Option (A) is the correct answer.

Explanation:

When weak base NH_{3} is dissolved in water then the reaction will be as follows.

       NH_{3} + H_{2}O \rightarrow NH^{+}_{4} + OH^{-}

When NH_{3} is compared with water then oxygen atom of H_{2}O being more electronegative in nature will keep its lone pair of electrons towards itself.

Hence, water will act as a neutral molecule and hence, NH_{3} will act as a stronger base as compared to H_{2}O.

On the other hand, OH^{-} will have both lone pair of electrons and a negative charge. Hence, its electron density is much more as compared to NH_{3} that only contains a lone pair of electron.

Therefore, NH_{3} will act as a weak base as compared to OH^{-}.

Thus, we can conclude that the statement OH^{-} is a stronger base than NH_{3}, is true concerning an aqueous solution of the weak base NH_{3}.

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No new substances are made
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One reaction involved in the conversion of iron ore to the metal is FeO(s) + CO(g) → Fe(s) + CO2(g) Use Hess’s Law to calculate
Ugo [173]

Answer:

\delta H_{rxn} = -66.0  \ kJ/mole

Explanation:

Given that:

3FeO_3_{(s)}+CO_{(g)} \to 2Fe_3O_4_{(s)} +CO_{2(g)} \  \ \delta H = -47.0 \ kJ/mole  -- equation (1)  \\ \\ \\ Fe_2O_3_{(s)} +3CO_{(g)} \to 2FE_{(s)} + 3CO_{2(g)}  \ \ \delta H = -25.0 \ kJ/mole  -- equation (2)  \\ \\ \\ Fe_3O_4_{(s)} + CO_{(g)} \to 3FeO_{(s)} + CO_{2(g)} \ \delta H = 19.0 \ kJ/mole  -- equation (3)

From equation (3) , multiplying (-1) with equation (3) and interchanging reactant with the product side; we have:

3FeO_{(s)} + CO_{2(g)}    \to    Fe_3O_4_{(s)} + CO_{(g)}   \ \delta H = -19.0 \ kJ/mole  -- equation (4)

Multiplying  (2) with equation (4) ; we have:

6FeO_{(s)} + 2CO_{2(g)}    \to    2Fe_3O_4_{(s)} + 2CO_{(g)}   \ \delta H = -38.0 \ kJ/mole  -- equation (5)

From equation (1) ; multiplying (-1) with equation (1); we have:

2Fe_3O_4_{(s)} +CO_{2(g)} \to     3FeO_3_{(s)}+CO_{(g)}   \  \ \delta H = 47.0 \ kJ/mole  -- equation (6)

From equation (2); multiplying (3) with equation (2); we have:

3 Fe_2O_3_{(s)} +9CO_{(g)} \to 6FE_{(s)} + 9CO_{2(g)}  \ \ \delta H = -75.0 \ kJ/mole  -- equation (7)

Now; Adding up equation (5), (6) & (7) ; we get:

6FeO_{(s)} + 2CO_{2(g)}    \to    2Fe_3O_4_{(s)} + 2CO_{(g)}   \ \delta H = -38.0 \ kJ/mole  -- equation (5)

2Fe_3O_4_{(s)} +CO_{2(g)} \to     3FeO_3_{(s)}+CO_{(g)}   \  \ \delta H = 47.0 \ kJ/mole  -- equation (6)

3 Fe_2O_3_{(s)} +9CO_{(g)} \to 6FE_{(s)} + 9CO_{2(g)}  \ \ \delta H = -75.0 \ kJ/mole  -- equation (7)

<u>                                                                                                                      </u>

FeO  \ \ \ +  \ \ \ CO   \ \  \to   \ \ \ \ Fe_{(s)} + \ \ CO_{2(g)} \ \ \  \delta H = - 66.0 \ kJ/mole

<u>                                                                                                                     </u>

<u />

\delta H_{rxn} = \delta H_1 +  \delta H_2 +  \delta H_3    (According to Hess Law)

\delta H_{rxn} = (-38.0 +  47.0 + (-75.0)) \ kJ/mole

\delta H_{rxn} = -66.0  \ kJ/mole

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