Answer : The molar heat of solution of KCl is, 17.19 kJ/mol
Explanation :
First we have to calculate the heat of solution.

where,
q = heat produced = ?
c = specific heat capacity of water = 
= change in temperature = 0.360 K
Now put all the given values in the above formula, we get:


Now we have to calculate the molar heat solution of KCl.

where,
= enthalpy change = ?
q = heat released = 460.8 J
m = mass of
= 2.00 g
Molar mass of
= 74.55 g/mol

Now put all the given values in the above formula, we get:


Therefore, the molar heat of solution of KCl is, 17.19 kJ/mol
Answer : The time taken for the reaction is, 28 s.
Explanation :
Expression for rate law for first order kinetics is given by :
![k=\frac{2.303}{t}\log\frac{[A_o]}{[A]}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B2.303%7D%7Bt%7D%5Clog%5Cfrac%7B%5BA_o%5D%7D%7B%5BA%5D%7D)
where,
k = rate constant = 0.0632
t = time taken for the process = ?
= initial amount or concentration of the reactant = 1.28 M
= amount or concentration left time 't' = 
Now put all the given values in above equation, we get:


Therefore, the time taken for the reaction is, 28 s.
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