Answer:
(a) 22.3 torr; 5.6 torr; (b) 27.9 torr; (c) 77.7 % heptane; 23.3 % octane
(d) Heptane is more volatile than octane
Explanation:
We can use Raoult's Law to solve this problem.
It states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapour pressure of the pure component multiplied by its mole fraction. In symbols,
(a) Vapour pressure of each component
Let heptane be Component 1 and octane be Component 2.
(i) Moles of each component

(ii) Total moles

(iiii) Mole fractions of each component

(iv) Partial vapour pressures of each component

(b) Total pressure

(c) Mass percent of each component in vapour

The ratio of the mole fractions is the same as the ratio of the moles.

If we have 1 mol of vapour, we have 0.799 mol of heptane and 0.201 mol of octane

(d) Enrichment of vapour
The vapour is enriched in heptane because heptane is more volatile than octane.
Charles law states that volume of gas is directly proportional to temperature at constant pressure
V/T = k
where V - volume , T - temperature and k - constant

where parameters for the first instance are on the left side and parameters for the second instance are on the right side of the equation
in the question it states that the temperature has been increased from 278 K to 231 K but it should actually be temperature is decreased from 278 K to 308 K
substituting the values in the equation

V = 462 cm³
the answer should be D. 462 cm³
Answer:
See explanation
Explanation:
All molecules possess the London dispersion forces. However London dispersion forces is the only kind of intermolecular interaction that exists in nonpolar substances.
So, the only kind of intermolecular interaction that exists in dimethyl ether is London dispersion forces.
As for ethyl alcohol, the molecule is polar due to the presence of polar O-H bond. In addition to London dispersion forces, dipole-dipole interactions and specifically hydrogen bonding also occurs between the molecules.
Because ethyl alcohol is polar, it is more soluble in water than dimethyl ether.