(a) The work done by the nitrogen against external pressure is 126.66 J.
(b) The change in the internal energy of the system is -2,466.66 J.
The given parameters:
- <em>Mass of the compound, = 2.25 g</em>
- <em>External pressure, P = 1.0 atm = 101325 Pa</em>
- <em>Density of Nitrogen gas, ρ = 1.165 g/L</em>
- <em>Temperature of the Nitrogen gas, T = 20⁰C</em>
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The molar mass of the given compound is calculated as follows;
NaN₃ = 23+ (14 x 3) = 65 g/mol
65 g -------------- 42
2.25 g ------------- ?

The volume of the nitrogen gas is calculated as follows;


The work done by the nitrogen against external pressure is calculated as follows;

The change in the internal energy of the system is calculated by applying first law of thermodynamics as follows;

Learn more about first law of thermodynamics here: brainly.com/question/2965070