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Alex_Xolod [135]
4 years ago
10

Suppose that the C=O group in a peptide bond can be regarded as isolated from the rest of the molecule. Given that the force con

stant of the bond in a carbonyl group is 908 N m−1 , calculate the vibrational frequency of (a) 12C=16O and (b) 13C=16O.

Chemistry
1 answer:
Stella [2.4K]4 years ago
4 0

Answer:

a) v = 1497.2 cm^-1

b) v = 1465 cm^-1

Explanation:

In the attached image is the procedure explained to reach the answer.

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proton:

a stable subatomic particle occurring in all atomic nuclei, with a positive electric charge equal in magnitude to that of an electron, but of opposite sign.

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What is the molar mass of a gas if 0.281 g of the gas occupies a volume of 125 ml at a temperature 126 °c and a pressure of 777
AleksAgata [21]
<em>Answer :</em> 72.05 g/mol
<span>
<em>Explanation : </em>

Let's </span>assume that the given gas is an ideal gas. Then we can use ideal gas equation,<span>
PV = nRT<span>
</span>
Where, 
P = Pressure of the gas (Pa)
V = volume of the gas (m³)
n = number of moles (mol)
R = Universal gas constant (8.314 J mol</span>⁻¹ K⁻¹)<span>
T = temperature in Kelvin (K)
<span>
The given data for the gas </span></span>is,<span>
P = 777 torr = 103591 Pa
V = </span>125 mL = 125 x 10⁻⁶ m³<span>
T = (</span>126 + 273<span>) = 399 K
R = 8.314 J mol</span>⁻¹ K⁻¹<span>
n = ?

By applying the formula,
103591 Pa x  </span>125 x 10⁻⁶ m³ = n x 8.314 J mol⁻¹ K⁻¹ x 399 K<span>
                                          n = 3.90 x 10</span>⁻³<span> mol

</span>Moles (mol) = mass (g) / molar mass (g/mol)<span>

Mass of the gas = </span><span>0.281 g
</span>Moles of the gas = 3.90 x 10⁻³ mol
<span>Hence,
   molar mass of the gas = mass / moles
                                          = 0.281 g / </span>3.90 x 10⁻³ mol
<span>                                          = 72.05 g/mol

</span>
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