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leonid [27]
3 years ago
12

In an ionic compound, the size of the ions affects the internuclear distance (the distance between the centers of adjacent ions)

, which affects lattice energy (a measure of the attractive force holding those ions together).
Based on ion sizes, arrange these compounds by their expected lattice energy.
Note that many sources define lattice energies as negative values. Please arrange by the magnitude and ignore the sign.
a) Li₂S
b) Cs₂S
c) K₂S
d) Na₂S
e) Rb₂S
Chemistry
1 answer:
Zielflug [23.3K]3 years ago
5 0

Answer:

Li2S>Na2S>K2S>Rb2S>Cs2S

Explanation:

Lattice Energy is a type of potential energy which may be defined in as, energy that is required to break apart an ionic solid and convert its component atoms into gaseous ions. More technically, it is a measure of the energy contained in the crystal lattice of a compound, equal to the energy that would be released if the component ions were brought together from infinity.

Lattice energy of ionic compounds decreases with increasing ionic sizes. Since the anion is the same, we consider increase in cation sizes. We discover that for gtoi 1 cations; Li+<Na+<K+<Rb+<Cs+. The ionic lattice energy decreases in the reverse order. Li2S will show the largest lattice energy since it contains the smallest cation in the list.

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Combustion of hydrocarbons such as dodecane (C12H26) produces carbon dioxide, a "greenhouse gas." Greenhouse gases in the Earth'
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Answer:

A. 2C12H26(l) + 37O2(g) —> 24CO2(g) + 26H2O(g)

B. 761.42 L

Explanation:

A. Step 1:

The equation for the reaction.

C12H26(l) + O2(g) —> CO2(g) + H2O(g)

A. Step 2:

Balancing the equation.

The equation can be balance as follow:

C12H26(l) + O2(g) —> CO2(g) + H2O(g)

There are 12 atoms of C on the left side and 1 atom on the right side. It can be balance by putting 12 in front of CO2 as illustrated below:

C12H26(l) + O2(g) —> 12CO2(g) + H2O(g)

There are 26 atoms of H on the left side and 2 atoms on the right side. It can be balance by putting 13 in front of H2O as illustrated below:

C12H26(l) + O2(g) —> 12CO2(g) + 13H2O(g)

Now, there are a total of 37 atoms of O2 on the right side and 2 atoms on the left. It can be balance by putting 37/2 in front of O2 as illustrated below:

C12H26(l) + 37/2O2(g) —> 12CO2(g) + 13H2O(g)

Multiply through by 2 to clear the fraction from the equation.

2C12H26(l) + 37O2(g) —> 24CO2(g) + 26H2O(g)

Now the equation is balanced

B. Step 1:

We'll by obtaining the number of mole of C12H26 in 0.450 kg of C12H26. This is illustrated below:

Molar Mass of C12H26 = (12x12) + (26x1) = 144 + 26 = 170g/mol

Mass of C12H26 = 0.450 kg = 0.450x1000 = 450g

Number of mole of C12H26 =?

Number of mole = Mass/Molar Mass

Number of mole of C12H26 = 450/170

Number of mole of C12H26 = 2.65 moles

B. Step 2:

Determination of the number of mole of CO2 produced by the reaction. This is illustrated below:

2C12H26(l) + 37O2(g) —> 24CO2(g) + 26H2O(g)

From the balanced equation above,

2 moles of C12H26 produced 24 moles of CO2.

Therefore, 2.65 moles of C12H26 will produce = (2.65x24)/2 = 31.8 moles of CO2.

B. Step 3:

Determination of the volume of CO2 produced by the reaction.

Pressure (P) = 1 atm

Temperature (T) = 19°C = 19°C + 273 = 292K

Gas constant (R) = 0.082atm.L/Kmol

Number of mole (n) = 31.8 moles

Volume (V) =?

The volume of CO2 produced by the reaction can b obtained by applying the ideal gas equation as follow:

PV = nRT

1 x V = 31.8 x 0.082 x 292

V = 761.42 L

Therefore, the volume of CO2 produced is 761.42 L

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