Question

In an ionic compound, the size of the ions affects the internuclear distance (the distance between the centers of adjacent ions), which affects lattice energy (a measure of the attractive force holding those ions together).
Based on ion sizes, arrange these compounds by their expected lattice energy.
Note that many sources define lattice energies as negative values. Please arrange by the magnitude and ignore the sign.
a) Li₂S
b) Cs₂S
c) K₂S
d) Na₂S
e) Rb₂S

Answer 1

Answer:

Li2S>Na2S>K2S>Rb2S>Cs2S

Explanation:

Lattice Energy is a type of potential energy which may be defined in as, energy that is required to break apart an ionic solid and convert its component atoms into gaseous ions. More technically, it is a measure of the energy contained in the crystal lattice of a compound, equal to the energy that would be released if the component ions were brought together from infinity.

Lattice energy of ionic compounds decreases with increasing ionic sizes. Since the anion is the same, we consider increase in cation sizes. We discover that for gtoi 1 cations; Li+<Na+<K+<Rb+<Cs+. The ionic lattice energy decreases in the reverse order. Li2S will show the largest lattice energy since it contains the smallest cation in the list.