Answer:The equilibrium constant for a given reaction is [concentration of products]/[concentration of reactants].
Explanation:
Equilibrium constant=[concentration of products]/[concentration of reactants]
The concentration of reactant molecules is maximum at time 0 and it decreases as the reaction proceeds, The concentration of product molecules increases.At equilibrium the concentration of reactants and products are equal.
All the changes would occur in accordance with the LeChateliers principle.
For the given reaction the following changes would occur:
a When CO is removed from the reaction mixture so the reaction would shift towards right that is in forward direction as we are decreasing the concentration of CO so the system would try to increase the concentration of CO and that can happen by more production of CO.
b Since the above reaction is an endothermic reaction so when we would be adding heat to the system that is when we would increase the temperature the reaction would shift forwards as more heat energy is absorbed by reactants to form more products.
c When more CO₂ is added so more amount of reactants are added to the system so the system would try to decrease the amount of reactants that is CO₂ and hence more amount of products would be formed.The reaction would shift in forward direction.
d Since this reaction is endothermic in nature so when we remove the heat from reaction hence even less amount of heat is present in the system and so the reaction shift in backward direction as the reaction cannot proceed without enough amount of heat.
Q1)
we can use the ideal gas law equation to find the total pressure of the system ;
PV = nRT
where P - pressure
V - volume - 7 x 10⁻³ m³
n - number of moles
total number of moles - 0.477 + 0.265 + 0.115 = 0.857 mol
R - universal gas constant - 8.314 Jmol⁻¹K⁻¹
T - temperature in K - 273 + 25 °C = 298 K
substituting the values in the equation
P x 7 x 10⁻³ m³ = 0.857 mol x 8.314 Jmol⁻¹K⁻¹ x 298 K
P = 303.33 kPa
1 atm = 101.325 kPa
Therefore total pressure - 303.33 kPa / 101.325 kPa/atm = 2.99 atm
Q2)
partial pressure is the pressure exerted by the individual gases in the mixture.
partial pressure for each gas can be calculated by multiplying the total pressure by mole fraction of the individual gas.
total number of moles - 0.477 + 0.265 + 0.115 = 0.857 mol
mole fraction of He -
mole fraction of Ne -
mole fraction of Ar -
partial pressure - total pressure x mole fraction
partial pressure of He - 2.99 atm x 0.557 = 1.67 atm
partial pressure of Ne - 2.99 atm x 0.309 = 0.924 atm
partial pressure of Ar - 2.99 atm x 0.134 = 0.401 atm
Answer:
Oxygen is the limiting reactant.
Explanation:
Based on the reaction:
C₁₂H₂₂O₁₁ + 12O₂ → 12CO₂ + 11H₂O
<em>1 mole of sucrose reacts with 12 moles of oxygen to produce 12 moles of CO₂ and 11 moles of H₂O.</em>
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10.0g of sucrose (Molar mass: 342.3g /mol) are:
10.0g C₁₂H₂₂O₁₁ × (1mole / 342.3g) = 0.0292 moles of C₁₂H₂₂O₁₁
And moles of 10.0g of oxygen (Molar mass: 32g/mol) are:
10.0g O₂ × (1mole / 32g) = 0.3125 moles of O₂
For a complete reaction of 0.0292 moles of C₁₂H₂₂O₁₁ you need (knowing 12 moles of oxygen react per mole of sucrose):
0.0292 moles of C₁₂H₂₂O₁₁ × (12 moles O₂ / 1 mole C₁₂H₂₂O₁₁) = <em>0.3504 moles of O₂</em>
As you have just 0.3125 moles of O₂, <em>oxygen is the limiting reactant.</em>
Answer:
-100 kJ
Explanation:
We can solve this problem by applying the first law of thermodynamics, which states that:
where:
is the change in internal energy of a system
Q is the heat absorbed/released by the system (it is positive if absorbed by the system, negative if released by the system)
W is the work done by the system (it is positive if done by the system, negative if done on the system)
For the system in this problem we have:
W = +147 kJ is the work done by the system
Q = +47 kJ is the heat absorbed by the system
So , its change in internal energy is:
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