Answer:
(D) chlorine has a greater ionization energy than sodium
Explanation:
Sodium is the element of the group 1 and period 3 which means that the valence electronic configuration is
.
Chlorine is the element of the group 17 and period 3 which means that the valence electronic configuration is
.
Ionization energy is the minimum amount of energy which is required to knock out the loosely bound valence electron from the isolated gaseous atom.
<u>Thus, removal of one electron in sodium is easy as it will gain noble gas configuration and become stable. But this case does not exist in chlorine and hence, chlorine has a greater ionization energy than sodium.</u>
So,
Sodium is much more apt to exist as a cation than chlorine because chlorine has a greater ionization energy than sodium.
Explanation:
It is given that aluminium nitrate and calcium chloride are mixed together with sodium phosphate.
And,
Let us assume that the solubility be "s". And, the reaction equation is as follows.

s = 
Also, 

s = 
This means that first, aluminium phosphate will precipitate.
Now, we will calculate the concentration of phosphate when calcium phosphate starts to precipitate out using the
expression as follows.
![K_{sp} = [Ca^{2+}]^{3}[PO^{3-}_{4}]^{2}](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%20%5BCa%5E%7B2%2B%7D%5D%5E%7B3%7D%5BPO%5E%7B3-%7D_%7B4%7D%5D%5E%7B2%7D)
![2.0 \times 10^{-29} = (0.016)^{3}[PO^{3-}_{4}]^{2}](https://tex.z-dn.net/?f=2.0%20%5Ctimes%2010%5E%7B-29%7D%20%3D%20%280.016%29%5E%7B3%7D%5BPO%5E%7B3-%7D_%7B4%7D%5D%5E%7B2%7D)
![2.0 \times 10^{-29} = 4.096 \times 10^{-6} \times [PO^{3-}_{4}]^{2}](https://tex.z-dn.net/?f=2.0%20%5Ctimes%2010%5E%7B-29%7D%20%3D%204.096%20%5Ctimes%2010%5E%7B-6%7D%20%5Ctimes%20%5BPO%5E%7B3-%7D_%7B4%7D%5D%5E%7B2%7D)
= 
=
M
Similarly, calculate the concentration of aluminium at this concentration of phosphate as follows.

![K_{sp} = [Al^{3+}][PO^{3-}_{4}]](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%20%5BAl%5E%7B3%2B%7D%5D%5BPO%5E%7B3-%7D_%7B4%7D%5D)
![9.84 \times 10^{-21} = [Al^{3+}] \times 2.21 \times 10^{-12}](https://tex.z-dn.net/?f=9.84%20%5Ctimes%2010%5E%7B-21%7D%20%3D%20%5BAl%5E%7B3%2B%7D%5D%20%5Ctimes%202.21%20%5Ctimes%2010%5E%7B-12%7D)
M
Thus, we can conclude that concentration of aluminium will be
M when calcium begins to precipitate.
The first one is the correct answer: <span>The potential energy of the products is greater than that of the reactants and the change in enthalpy is positive.<span> </span></span>
<u>Correct Answer:</u><u> Option (A) </u>
H₂S : SO₂ = 2:2 and,
O₂: H₂O = 3:2
Explanation:
The mole ratio is the ratio of coefficients of the compounds involved in the reaction. <u>R</u><u><em>eactants,</em></u><u> as on the left hand side of the chemical reaction which reach to for</u>m new products.
In the given reaction,
2H₂S + 3O₂ ⇒ 2SO₂ + 2H₂O
<u>The reactants are :</u> H₂S (hydrogen sulphide) & O₂ (oxygen)
<u>The products are :</u> SO₂ (sulphur dioxide) & H₂O (water)
- 2 moles of hydrogen sulphide react with 3 moles of oxygen
- 2 moles of sulphur dioxide & 2 moles of water are produced
Therefore correct option is
H₂S : SO₂ = 2:2 and,
O₂: H₂O = 3:2
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TRUE