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Elden [556K]
3 years ago
10

(a) The rate of the reaction in terms of the "disappearance of reactant" includes the change in the concentration of the

Chemistry
1 answer:
Vaselesa [24]3 years ago
6 0

Answer:

The average rate of the reaction in terms of disappearance of A is 0.0004 M/s.

Explanation:

Average rate of the reaction is defined as ratio of change in concentration of reactant with respect to given interval of time.

R_{avg}=-\frac{[A]_2-[A]_1}{t_2-t_1}

Where :

A_1 = initial concentration of reactant at t_1.

A_2 = Final concentration of reactant at t_2.

2A+3B → 3C+2D

R_{avg}=-\frac{1}{2}\frac{[A]_2-[A]_1}{t_2-t_1}

The concentration of A at (t_1=0 seconds ) = A_1=0.0400 M

The concentration of A at (t_2=20 seconds ) = A_2=0.0240 M

The average rate of reaction in terms of the disappearance of reactant A in an interval of 0 seconds to 20 seconds is :

R_{avg}=-\frac{1}{2}\times \frac{0.0240 M-0.0400 M}{20-0}=0.0004 M/s

The average rate of the reaction in terms of disappearance of A is 0.0004 M/s.

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Answer:

The analytical concentrations of thiocyanate ions:

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Moles (n)=Molarity(M)\times Volume (L)

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(1 mL = 0.001L)

Molarity of the sodium thiocyanate = 4.8\times 10^{-4} M

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1 mole of ferric nitrate has 3 moles of ferric ions.

So number of moles of ferric ions in 0.00042 moles of ferric nitrate is :

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Total volume by adding all three volumes of solutions = V

V = 5.00 mL + 2.00 mL + 13.00 mL = 20.00 mL = 0.020 L

The analytical concentrations of thiocyanate ions:

[SCN^-]=\frac{2.4\times 10^{-6}mol}{0.020 L}=0.00012 mol/L

The analytical concentrations of ferric ions:

[Fe^{3+}]=\frac{0.00126 mol}{0.020 L}=0.063 mol/L

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