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tekilochka [14]
4 years ago
9

Biacetyl, the flavoring that makes margarine taste "just like butter," is extremely stable at room temperature, but at 200°C it

undergoes a first-order breakdown with a half-life of 9.0 min. An industrial flavor-enhancing process requires that a butter-flavored food be heated briefly at 200°C. How long can the food be heated at this temperature and retain 74% of its buttery flavor?
Chemistry
1 answer:
SIZIF [17.4K]4 years ago
5 0

Answer:

3.91 minutes

Explanation:

Given that:

Biacetyl breakdown with a half life of 9.0 min after undergoing first-order reaction;

As we known that the half-life for first order is:

t__{1/2}}= \frac{0.693}{k}

where;

k = constant

The formula can be re-written as:

k = \frac{0.693}{t__{1/2}}

k = \frac{0.693}{9.0 min}

k = 0.077 min^{-1}

Let the initial amount of butter flavor in the food be (N_0) = 100%

Also, the amount of butter flavor retained at 200°C (N_t)= 74%

The rate constant k = 0.077 min^{-1}

To determine how long can the food be heated at this temperature and retain 74% of its buttery flavor; we use the formula:

\frac{N_t}{N_0}= -kt

t = - (\frac{1}{k}*In\frac{N_t}{N_0}  )

Substituting our values; we have:

t = - (\frac{1}{0.077}*In\frac{74}{100}  )

t = 3.91 minutes

∵ The time needed for the food to be heated at this temperature and retain 74% of its buttery flavor is 3.91 minutes

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Answer:

1,812 wt%

Explanation:

The reactions for this titration are:

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I₃⁻ + 2S₂O₃⁻ → 3I⁻ + S₄O₆²⁻

The moles in the end point of S₂O₃⁻ are:

0,01302L×0,03428M Na₂S₂O₃ = 4,463x10⁻⁴ moles of S₂O₃⁻. As 2 moles of S₂O₃⁻ react with 1 mole of I₃⁻, the moles of I₃⁻ are:

4,463x10⁻⁴ moles of S₂O₃⁻×\frac{1molI_{3}^-}{2molS_{2}O_{3}^-} = 2,2315x10⁻⁴ moles of I₃⁻

As 2 moles of Ce⁴⁺ produce 1 mole of I₃⁻, the moles of Ce⁴⁺ are:

2,2315x10⁻⁴ moles of I₃⁻×\frac{2molCe^{4+}}{1molI_{3}^-} = 4,463x10⁻⁴ moles of Ce(IV). These moles are:

4,463x10⁻⁴ moles of Ce(IV)×\frac{140,116g}{1mol} = <em>0,0625 g of Ce(IV)</em>

As the sample has a 3,452g, the weight percent is:

0,0625g of Ce(IV) / 3,452g × 100 = <em>1,812 wt%</em>

I hope it helps!

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A buffer solution is prepared by placing 5.86 grams of sodium nitrite and 32.6 mL of a 4.90 M nitrous acid solution into a 500.0
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This question is incomplete, the complete question is;

A buffer solution is prepared by placing 5.86 grams of sodium nitrite and 32.6 mL of a 4.90 M nitrous acid solution into a 500.0 mL volumetric flask and diluting to the calibration mark. If 10.97 mL of a 1.63 M solution of potassium hydroxide is added to the buffer, what is the final pH? The Ka for nitrous acid = 4.6 × 10⁻⁴.

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Explanation:

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Initial moles of HNO2 = 32.6/1000 × 4.90 = 0.15974 mol

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pH = -log ka + log( moles of NO2- / moles of HNO2 )

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