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QveST [7]
4 years ago
8

The heat of vaporization of 1–pentanol is 55.5 kJ/mol, and its entropy of vaporization is 148 J/K•mol. What is the approximate b

oilingpoint of 1–pentanol?
Chemistry
1 answer:
tensa zangetsu [6.8K]4 years ago
3 0

Answer:

375 K

Explanation:

Using the experssion shown below as:

\Delta G^0=\Delta H^0_{vap}-T\Delta S^0_{vap}

At vaporization point, the liquid and the gaseous phase is in the equilibrium.

Thus,

\Delta G^0=0

So,

Delta H^0_{vap}=T\Delta S^0_{vap}

Given that:

Delta H^0_{vap}=55.5\ kJ/mol

Also, 1 kJ = 10³ J

So,

Delta H^0_{vap}=55500\ J/mol

\Delta S^0_{vap}=148\ J/K.mol

So, temperature is :

T=\frac{Delta H^0_{vap}}{\Delta S^0_{vap}}

T=\frac{55500}{148}

<u>T= 375 K</u>

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