Answer:The product formed on reaction with hydroxide ion as nucleophile is 2R-hexane-2-ol.
The product formed on reaction with water would be a 50:50 mixture of
2S-hexane-2-ol. and 2R-hexane-2-ol.
Explanation:
2S-iodohexane on reactiong with hydroxide ion would undergo SN² substitution reaction that is substitution bimolecular. Hydroxide ion has a negative charge and hence it is a quite good nucleophile .
The rate of a SN² reaction depends on both the substrate and nucleophile . Here the substrate is a secondary carbon center having Iodine as a leaving group.SN² reaction takes place here as hydroxide ion is a good nucleophile and it can attack the secondary carbon center from the back side leading to the formation of 2R-hexane-2-ol.
In a SN² reaction since the the nucleophile attacks from the back-side so the product formation takes place with the inversion of configuration.
When the same substrate S-2-iodohexane undergoes a substitution reaction with water as a nucleophile then the reaction occurs through (SN¹) substitution nucleophilic unimolecular mechanism .
The rate of a SN¹ reaction depends only on the nature of substrate and is independent of the nature of nucleophile.
The SN¹ reaction is a 2 step reaction , in the first step leaving group leaves leading to the formation of a carbocation and once the carbocation is formed then any weaker nucleophile or even solvent molecules can attack leading the formation of products.
In this case a secondary carbocation would be generated in the first step and then water will attack this carbocation to form the product in the second step.
The product formed on using water as a nucleophile would be a racemic mixture of R and S isomers of hexane -2-ol in 50:50 ratio. The two products formed would be 2R-hexane-2-ol and 2S-hexane-2-ol.
Kindly refer the attachment for reaction mechanism and structure of products.
Answer:
A temporary magnet allows the user to determine when it is magnetic.
Zero degree celcius = 273.15 degree kelvin
Simply, to get the value of 45.1 degree celcius in kelvin, we will add 273.15 to the given value (45.1).
Degree in kelvin = 45.1 + 273.15 = 318.25 degree kelvin
Approximating to the nearest tenth, the value will be 318.3 degree kelvin
Let's think, if you have a candle ( that is not blown out ) the physical properties are the candles mass and hence ( hence of the candle is the stiffness of the candle), weight, length, density, surface friction ( force resisting the relative motion of solid surface), and the energy content. You then, need to go to bed, so, therefore, you want to blow the candle out. Once you blow the candle out, the candle is evidently going to have at least a couple of different physical properties, than before it was blown out. The physical properties are a different color, the length of the candle, the texture, you could also apply the mass of the candleholder, and then, the mass of the candleholder and the candle, last but not least, the mass of just the candle. Once you observe the candle, you should be able to plug in those observations into the physical properties. As to, because you asked' what are the physical properties of a candle that has been blown out... We are going to assume that we did observe the candle, and the length of the candle in cm, after being blown out is 30cm. (12 inches; customary). Next, that the color of the candle is the same (let us say the original color is taffy pink). We can then say that the texture of the candle is waxy and the top and smooth as you get to the bottom ( the texture depends on how long the candle was burning, but we are saying that we lit the candle, and then immediately blew the flame out ) . We now have the mass of the candleholder, which will scientificity stay the same. Now, for the mass of the candleholder and the candle, that all depends of how long you let it burn ( remember, we are saying we lit the wick and then immediately blew the fame out ). So, the candle really didn't change is mass, so, therefore, wouldn't affect the mass of the candleholder including the candle. That also goes to the mass of the candle.
