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Iteru [2.4K]
3 years ago
8

Which of the following solutions would have the highest osmotic pressure?

Chemistry
1 answer:
Gennadij [26K]3 years ago
8 0

Answer:

Option d. 0.10 m Cr₂(SO₄)₃

Explanation:

Formula for the osmotic pressure is determined as:

π = M . R . T . i

So you have to take account the i (Van't Hoff factor, numbers of ions dissolved)

  • CH₄N₂O → 0.35 m

Urea is an organic compound, so the i value is 1

  • H₂O → The i is also 1
  • Zn(CH₃COO)₂ → 0.15 m

Zync acetate can be dissociated:

Zn(CH₃COO)₂  →  1Zn²⁺  + 2CH₃COO⁻

In this case, the i is 3. (you see, the stoichiometry of ions)

Cr₂(SO₄)₃ →  0.10 m

Chromium sulfate is dissociated:

Cr₂(SO₄)₃ →  2Cr³⁺  +  3SO₄⁻²

i = 5

BaI₂ → 0.16 m

BaI₂ →  1Ba²⁺  +  2I⁻

i = 3

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Answer:

a. +6;

b. +5;

c. +3.

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Start with elements with well-known oxidation states.

The oxidation state on oxygen O in compounds is mostly -2. Common exceptions include:

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The oxidation state on group 1 metals (Li, Na, K, etc.) in compounds is mostly +1.

The oxidation state on group 2 metals (Be, Mg, Ca, etc.) in compounds is mostly +2.

Barium Ba is a group 2 metal. The oxidation state on Ba in the compound BaSO₄ is expected to be +2.

The oxidation state on hydrogen H in compounds is mostly +1. The oxidation state on H might be negative when it is bonded to metals.  

The oxidation state on halogens (F, Cl, Br, etc.) is mostly -1. The oxidation state may vary when the halogen is bonded to oxygen or another halogen element.

Compounds are neutral. The oxidation state on all atoms in a compound shall add up to 0. Both BaSO₄ and HClO₂ are neutral.

<h3>BaSO₄</h3>

Oxidation states:

  • Ba: +2;
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Let the oxidation state on S be x.

2 + x + 4 × (-2) = 0;

x = 6.

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<h3>HClO₂</h3>

Oxidation states:

  • H: +1;
  • Cl here is bonded to oxygen. The oxidation state on chlorine Cl is to be determined;
  • O: -2.

Let the oxidation state on Cl be x.

<em>Refer to the equation in BaSO₄ as an example. Try setting up the equation on your own. </em>

x = 3.

Hence, the oxidation state on Cl is +3.

<h3>PO₄³⁻</h3>

Ions carry charge. Oxidation states on atoms in an ion shall add up to the charge of the ion. The superscript of an ion shows its charge. The superscript 3- in the phosphate ion shows that the ion carries a charge of -3.

Oxidation states:

  • The oxidation state on P is to be found;
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Let the oxidation state on P be x.

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x = 5.

Hence, the oxidation state on P is +5.

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Similarly, ionic substances follow the same pattern. Since the net charge of ionic salts should be equal to 0 and each element has a definite number of valence electrons in its shell all the time, the ions combine in a way, so that cations balance the charge of anions.

Essentially, the law of definite proportions is applicable and will be applicable in the future, since we know that each element has a fixed number of valence electrons in its ground state.

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