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bogdanovich [222]
3 years ago
15

Potassium hydrogen phthalate is a solid, monoprotic acid frequently used in the laboratory to standardize strong base solutions.

it has the unwieldy formula of khc8h4o4. this is often written in shorthand notation as khp. how many grams of khp are needed to exactly neutralize 28.5 ml of a 0.483 m barium hydroxide solution ?
Chemistry
2 answers:
Norma-Jean [14]3 years ago
6 0

2 KHP(aq) + Ba(OH)_{2}(aq) ---> KP_{2}Ba (aq) + 2 H_{2}O (l)\

Moles of Ba(OH)_{2}=0.483 \frac{mol}{L} * 28.5 mL *\frac{1 L}{1000mL}  = 0.0138 mol Ba(OH)_{2}

Mass of KHP = 0.0138 mol Ba(OH)_{2} * \frac{2 mol KHP}{1 mol Ba(OH)_{2}}  * \frac{204.22 g KHP}{1mol KHP}

= 5.64 g KHP

Tamiku [17]3 years ago
6 0

Answer:

5.64g of KHP

Explanation:

2KHC8H4O4 + Ba (OH)2 → Ba (KC8H4O4)2 + 2H2O

Number of moles (n) = concentration × volume

Number of moles (n) = 0.483× 28.5/1000= 0.0138 moles of Ba(OH)2

From the reaction equation:

2 moles of KHP reacted with 1 moles of Ba(OH)2

x moles of KHP will react with 0.0138 moles of Ba(OH)2

x= 2× 0.0138/1 = 0.0276 moles

Molar mass of KHP = 204.22 g/mol

Therefore mass of KHP = 204.22 g/mol × 0.0276 moles= 5.64g of KHP

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The question is incomplete, here is the complete question:

Burning a compound of calcium, carbon, and nitrogen in oxygen in a combustion train generates calcium oxide (CaO), carbon dioxide (CO_2), nitrogen dioxide (NO_2), and no other substances. A small sample gives 2.389 g CaO, 1.876 g CO_2, and 3.921 g NO_2 Determine the empirical formula of the compound.

<u>Answer:</u> The empirical formula for the given compound is CaCN_2

<u>Explanation:</u>

The chemical equation for the combustion of compound having calcium, carbon and nitrogen follows:

Ca_xC_yN_z+O_2\rightarrow CaO+CO_2+NO_2

where, 'x', 'y' and 'z' are the subscripts of calcium, carbon and nitrogen respectively.

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Mass of CO_2=1.876g

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We know that:

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Molar mass of nitrogen dioxide = 46 g/mol

<u>For calculating the mass of carbon:</u>

In 44g of carbon dioxide, 12 g of carbon is contained.

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In 46 g of nitrogen dioxide, 14 g of nitrogen is contained.

So, in 3.921 g of nitrogen dioxide, \frac{14}{46}\times 3.921=1.193g of nitrogen will be contained.

<u>For calculating the mass of calcium:</u>

In 56 g of calcium oxide, 40 g of calcium is contained.

So, in 2.389 g of calcium oxide, \frac{40}{56}\times 2.389=1.706g of calcium will be contained.

To formulate the empirical formula, we need to follow some steps:

  • <u>Step 1:</u> Converting the given masses into moles.

Moles of Calcium =\frac{\text{Given mass of Calcium}}{\text{Molar mass of Calcium}}=\frac{1.706g}{40g/mole}=0.0426moles

Moles of Carbon =\frac{\text{Given mass of Carbon}}{\text{Molar mass of Carbon}}=\frac{0.5116g}{12g/mole}=0.0426moles

Moles of Nitrogen = \frac{\text{Given mass of Nitrogen}}{\text{Molar mass of Nitrogen}}=\frac{1.193g}{14g/mole}=0.0852moles

  • <u>Step 2:</u> Calculating the mole ratio of the given elements.

For the mole ratio, we divide each value of the moles by the smallest number of moles calculated which is 0.0426 moles.

For Calcium = \frac{0.0426}{0.0426}=1

For Carbon = \frac{0.0426}{0.0426}=1

For Nitrogen = \frac{0.0852}{0.0426}=2

  • <u>Step 3:</u> Taking the mole ratio as their subscripts.

The ratio of Ca : C : N = 1 : 1 : 2

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