Answer:
The calorimeter constant is = 447 J/°C
Explanation:
The heat absorbed or released (Q) by water can be calculated with the following expression:
Q = c × m × ΔT
where,
c is the specific heat
m is the mass
ΔT is the change in temperature
The water that is initially in the calorimeter (w₁) absorbs heat while the water that is added (w₂) later releases heat. The calorimeter also absorbs heat.
The heat absorbed by the calorimeter (Q) can be calculated with the following expression:
Q = C × ΔT
where,
C is the calorimeter constant
The density of water is 1.00 g/mL so 50.0 mL = 50.0 g. The sum of the heat absorbed and the heat released is equal to zero (conservation of energy).
Qabs + Qrel = 0
Qabs = - Qrel
Qcal + Qw₁ = - Qw₂
Qcal = - (Qw₂ + Qw₁)
Ccal . ΔTcal = - (cw . mw₁ . ΔTw₁ + cw . mw₂ . ΔTw₂)
Ccal . (30.31°C - 22.6°C) = - [(4.184 J/g.°C) × 50.0 g × (30.31°C - 22.6°C) + (4.184 J/g.°C) × 50.0 g × (30.31°C - 54.5°C)]
Ccal = 447 J/°C
The pH of the buffer is 6.1236.
Explanation:
The strength of any acid solution can be obtained by determining their pH. Even the buffer solution strength of the weak acid can be determined using pH. As the dissociation constant is given, we can determine the pKa value as the negative log of dissociation constant value.
![pKa=-log[H] = - log [ 5.66 * 10^{-7}]\\ \\pka = 7 - log (5.66)=7-0.753=6.247\\\\pka = 6.247](https://tex.z-dn.net/?f=pKa%3D-log%5BH%5D%20%3D%20-%20log%20%5B%205.66%20%2A%2010%5E%7B-7%7D%5D%5C%5C%20%5C%5Cpka%20%3D%207%20-%20log%20%285.66%29%3D7-0.753%3D6.247%5C%5C%5C%5Cpka%20%3D%206.247)
The pH of the buffer can be known as
![pH = pK_{a} + log[\frac{[A-]}{[HA]}}]](https://tex.z-dn.net/?f=pH%20%3D%20pK_%7Ba%7D%20%2B%20log%5B%5Cfrac%7B%5BA-%5D%7D%7B%5BHA%5D%7D%7D%5D)
The concentration of ![[A^{-}] = Moles of [A]/Total volume = 0.608/2 = 0.304 M\\](https://tex.z-dn.net/?f=%5BA%5E%7B-%7D%5D%20%3D%20Moles%20of%20%5BA%5D%2FTotal%20volume%20%3D%200.608%2F2%20%3D%200.304%20M%5C%5C)
Similarly, the concentration of [HA] = 
Then the pH of the buffer will be
pH = 6.247 + log [ 0.304/0.404]
So, the pH of the buffer is 6.1236.
Answer:
2 Answers. The column is filled with the carrier (liquid or gas) before the sample is injected. Thus if there is no interaction between the sample and the column, then the fastest that the sample can get to the detector is the dead time denoted by tM in the diagram.
Iron bromide isn't considered magnetic because all iron compounds are not magnetic
Answer:
The boiling point increases with increased pressure up to the critical point, where the gas and liquid properties become identical.
