Explanation :
In thermodynamics, a system is region or part of space which is being studied and observed while the surrounding is the region or space around the system which interacts with the system.
Here in the experiment ,system which is observed is reaction or changes when citric acid and sodium bicarbonate are mixed together. And the mixing is carried out in the calorimeter which serves as a surrounding around the system.
The reason behind the using the calorimeter is measure the energy change occurring during the reaction.
12 times breathe give 240 ml of pure 
. Each breathe gives 20 ml of .
Let us consider, volume of air per breathe= x ml.
Pure from inhaled air= 
ml and Pure from exhaled air= 
ml.
Pure from inhaled and exhaled air= 20 ml
So, + = 20
Therefore, x = 55.5 ml
So, volume of air per breath= 55.5 ml.
Explanation:
i believe this is right. my bad if its not
