Answer:
ΔG°rxn = +50.8 kJ/mol
Explanation:
It is possible to obtain ΔG°rxn of a reaction at certain temperature from ΔH°rxn and S°rxn, thus:
<em>ΔG°rxn = ΔH°rxn - T×S°rxn (1)</em>
In the reaction:
2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l)
ΔH°rxn = 3×ΔHfNO2 + ΔHfH2O - (2×ΔHfHNO3 + ΔHfNO)
ΔH°rxn = 3×33.2kJ/mol + (-285.8kJ/mol) - (2×-207.0kJ/mol + 91.3kJ/mol)}
ΔH°rxn = 136.5kJ/mol
And S°:
S°rxn = 3×S°NO2 + S°H2O - (2×S°HNO3 + S°NO)
ΔH°rxn = 3×0.2401kJ/molK + (0.0700kJ/molK) - (2×0.146kJ/molK + 0.2108kJ/molK)
ΔH°rxn = 0.2875kJ/molK
And replacing in (1) at 298K:
ΔG°rxn = 136.5kJ/mol - 298K×0.2875kJ/molK
<em>ΔG°rxn = +50.8 kJ/mol</em>
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Answer:
5.56 × 10⁻⁸
Explanation:
Step 1: Given data
- Concentration of the weak acid (Ca): 0.187 M
Step 2: Calculate the concentration of H⁺
We will use the following expression.
pH = -log [H⁺]
[H⁺] = antilog -pH = antilog -3.99 = 1.02 × 10⁻⁴ M
Step 3: Calculate the acid dissociation constant (Ka)
We will use the following expression.
![Ka = \frac{[H^{+}]^{2} }{Ca} = \frac{(1.02 \times 10^{-4})^{2} }{0.187} = 5.56 \times 10^{-8}](https://tex.z-dn.net/?f=Ka%20%3D%20%5Cfrac%7B%5BH%5E%7B%2B%7D%5D%5E%7B2%7D%20%7D%7BCa%7D%20%3D%20%5Cfrac%7B%281.02%20%5Ctimes%2010%5E%7B-4%7D%29%5E%7B2%7D%20%7D%7B0.187%7D%20%3D%205.56%20%5Ctimes%2010%5E%7B-8%7D)
The first word could be: pairs and the second: relax
To determine mass of the given number of atoms of mercury, we need a factor that would relate the number of atoms to number of moles. In this case, we use the Avogadro's number. It is a <span>number that represents the
number of units in one mole of any substance. This has the value of 6.022 x
10^23 units / mole. The number of units could be atoms, molecules, ions or electrons. To convert into mass, we use the given amu of mercury since it is equal to grams per mole. We calculate as follows:
</span>3.0 x 10^10 atoms ( 1 mol / 6.022 x 10^23 atoms ) ( 200.59 g / 1 mol ) = 9.99x10^-12 g Hg
Answer:
The coordination sphere of a complex consists of <u><em>the central metal ion and the ligands bonded to it.</em></u>
Explanation:
The Coordination Compounds are sets of a central metal ion attached to a group of molecules or ions that surround it. They are also called metal complexes or simply complexes. Then they are compounds that have a central atom surrounded by a group of molecules or ions, the latter called ligands.
The central atom must have empty orbitals capable of accepting pairs of electrons, with the transition metals being the ones with the greatest tendency. Because of this, they can act as Lewis acids (electron pair acceptors). The ligands have unshared electron pairs, then acting as Lewis bases (electron pair donors).
When forming a complex, it is said that the ligands coordinate to the metal and the central metal and the ligands attached to it constitute the coordination sphere of the complex.
Finally, <u><em>the coordination sphere of a complex consists of the central metal ion and the ligands bonded to it.</em></u>
