Explanation:
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Answer:
The product is cyclohexanol
Explanation:
Firstly,
A ketone undergo a borohydride reduction reaction to form an alcohol as below,
R-CO-R' ⇒ R-CO(OH)-R'
- IR Spectrum confirms that alcohol group is existed with the peak at 3400 cm⁻¹
- From 1H-NMR, the product has 10 hydrogen atoms, the MS suggest that the formula is C₅H₁₀O (M = 86). With this formula, the alcohol is monosaturated. Since, the substance already underwent reduction reaction, the only way to suggest a monosaturated compound is a cyclic alcohol. So the compound is cyclopentanol.
- Check with other spectroscopic properties,
- 3 signals of 13C NMR confirms the structure is symmetrical, δ 24.2, (-<u>C</u>H₂-CH₂-CH(CH₂-)-OH), δ 35.5 (-CH₂-<u>C</u>H₂-CH(CH₂-)-OH), δ 73.3 (-CH₂-CH₂-<u>C</u>H(CH₂-)-OH).
1.56 δ (4H, triplet) - (-C<u>H</u>₂-CH₂-CH-OH) ; triplet as coupling with 2 H,
1.78 δ (4H, multiplet) - (-CH₂-C<u>H</u>₂-CH-OH); multiplet as coupling with 2H of CH₂, 1 H of CH
3.24 δ (1H, quintet); - (-CH₂-CH₂-C<u>H</u>(CH₂-)-OH), coupling with4 H of 2 group of CH₂
3.58 δ (1H, singlet); - (-CH₂-CH₂-CH(CH₂-)-O<u>H</u>), hydrogen of alcohol group, not tend to coupling with other hydrogen
Answer:
Boiling water breaks intermolecular attractions and electrolysis breaks covalent bonds.
Explanation:
When water boils, hydrogen bonds are broken between adjacent water molecules. The hydrogen bond is an intermolecular bond between adjacent oxygen and hydrogen atoms of water molecules.
During electrolysis, water dissociates in the presence of electric current. Here, ions are formed in the process. Therefore, covalent bonds are broken here.
Answer:
Cohesive forces are greater than adhesive forces
Step-by-step explanation:
The attractive forces between water molecules and the wax on a freshly-waxed car (adhesive forces) are quite weak.
However, there are strong attractive forces (cohesive forces) between water molecules.
The water molecules are only weakly attracted to the wax, so the cohesive forces pull the water molecules together to form beads
.
2.1648 kg of CH4 will generate 119341 KJ of energy.
Explanation:
Write down the values given in the question
CH4(g) +2 O2 → CO2(g) +2 H20 (g)
ΔH1 = - 802 kJ
2 H2O(g)→2 H2O(I)
ΔH2= -88 kJ
The overall chemical reaction is
CH4 (g)+2 O2(g)→CO2(g)+2 H2O (I) ΔH2= -890 kJ
CH4 +2 O2 → CO2 +2 H20
(1mol)+(2mol)→(1mol+2mol)
Methane (CH4) = 16 gm/mol
oxygen (O2) =32 gm/mol
Here 1 mol CH4 ang 2mol of O2 gives 1mol of CO2 and 2 mol of 2 H2O
which generate 882 KJ /mol
Therefore to produce 119341 KJ of energy
119341/882 = 135.3 mol
to produce 119341 KJ of energy, 135.3 mol of CH4 and 270.6 mol of O2 will require
=135.3 *16
=2164.8 gm
=2.1648 kg of CH4
2.1648 kg of CH4 will generate 119341 KJ of energy