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Snezhnost [94]
3 years ago
9

A 1 liter solution contains 0.247 M nitrous acid and 0.329 M sodium nitrite. Addition of 0.271 moles of calcium hydroxide will:

(Assume that the volume does not change upon the addition of calcium hydroxide.)
a. Raise the pH slightly
b. Lower the pH slightly
c. Raise the pH by several units
d. Lower the pH by several units
e. Not change the pH
f. Exceed the buffer capacity
Chemistry
1 answer:
Inessa05 [86]3 years ago
4 0

Answer:

a. Raise the pH slightly

Explanation:

We know that

Pka of HNO2/KNO2 =3.39

Moles of HNO2 in the buffer=0.247 mol/L×1L=0.247 moles

Moles of NO2-=0.329mol/L×1L=0.329 moles

If 0.271 moles of Ca(OH)2 is added it will neutralise 0.136 moles of acid ,HNO2,remaining HNO2=0.247-0.136=0.111 moles

Moles of NO2- will increase as 0.0333 moles Ca(NO)2 will be formed =0.0333+0.036=0.0693 moles

pH=pka+log [base]/[acid]      {henderson -hasselbach equation}

=3.39+log (0.0693/0.0317)=3.39+0.34=3.73

pH=3.73

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What volume of 0.100 M HCl will react completely with 50.00 mL of 0.200 M NaOH?
skelet666 [1.2K]
Equation of reaction
Hcl+NaoH-->Nacl+H2O
1:1
Using the formula CaVa/CbVb=na/nb
Ca(Concentation of acid)= 0.100M
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Va=?
VB=50.00ml
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Urea (CH4N2O) is a common fertilizer that can be synthesized by the reaction of ammonia (NH3) with carbon dioxide as follows: 2N
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The question is incomplete, here is the complete question:

Urea (CH₄N₂O) is a common fertilizer that can be synthesized by the reaction of ammonia (NH₃) with carbon dioxide as follows: 2NH₃(aq) + CO₂(aq) → CH₄N₂O(aq) + H₂O(l) In an industrial synthesis of urea, a chemist combines 135.9 kg of ammonia with 211.4 kg of carbon dioxide and obtains 178.0 kg of urea.

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<u>Explanation:</u>

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}     .....(1)

  • <u>For ammonia:</u>

Given mass of ammonia = 135.9 kg = 135900 g    (Conversion factor:  1 kg = 1000 g)

Molar mass of ammonia = 17 g/mol

Putting values in equation 1, we get:

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  • <u>For carbon dioxide gas:</u>

Given mass of carbon dioxide gas = 211.4 kg = 211400 g

Molar mass of carbon dioxide gas = 44 g/mol

Putting values in equation 1, we get:

\text{Moles of carbon dioxide gas}=\frac{211400g}{44g/mol}=4804.54mol

The given chemical reaction follows:

2NH_3(aq.)+CO_2(aq,)\rightarrow CH_4N_2O(aq.)+H_2O(l)

By Stoichiometry of the reaction:

2 moles of ammonia reacts with 1 mole of carbon dioxide

So, 7994.12 moles of ammonia will react with = \frac{1}{2}\times 7994.12=3997.06mol of carbon dioxide

As, given amount of carbon dioxide is more than the required amount. So, it is considered as an excess reagent.

Thus, ammonia is considered as a limiting reagent because it limits the formation of product.

Hence, the limiting reactant is ammonia (NH_3)

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