0.1 M x 0.5L = 0.05 mols HCl.
Adding 25 mL 2M NaOH is
2M x 0.025 L = 0.05 mols NaOH.
What you want to do is to back off very slightly with the NaOH (you might try something like 24.95 mL which I calculate to give 0.00019 M or a pH of 3.7. Inching closer, 24.99 mL would leave H^+ of 4E-5 for pH 4.4. The problem here is two-fold.
hope it helps
There are one antibonding molecular orbitals present in molecular orbital model of c.
The cyclobutadiene has a pi system comprised of four individual atomic p - orbital and thus should have a four pi molecular orbitals. The compound is the prototypical antiaromatic hydrocarbon with 4 
- electrons . Its rectangular structure is the result of jahn teller reaction which disorder the molecule and lowers its symmetry , converting the triplet to a singlet ground state. It is a small annulene . The delocalisation energy of the electrons of the cyclobutene is predicted to be zero .
To learn more about antibonding molecular orbitals click here
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<span>C2Br2
First, we need to determine how many moles of the gas we have. For that, we'll use the Ideal Gas Law which is
PV = nRT
where
P = pressure (1.10 atm = 111458 Pa)
V = volume (10.0 ml = 0.0000100 m^3)
n = number of moles
R = Ideal gas constant (8.3144598 (m^3 Pa)/(K mol) )
T = Absolute temperature
Solving for n, we get
PV/(RT) = n
Now substituting our known values into the formula.
(111458 Pa * 0.0000100 m^3) / (288.5 K * 8.3144598 (m^3 Pa)/(K mol))
= (1.11458/2398.721652) mol
= 0.000464656 mol
Now let's calculate the empirical formula for this compound.
Atomic weight carbon = 12.0107
Atomic weight bromine = 79.904
Relative moles carbon = 13.068 / 12.0107 = 1.08802984
Relative moles bromine = 86.932 / 79.904 = 1.087955547
So the relative number of atoms of the two elements is
1.08802984 : 1.087955547
After dividing all numbers by the smallest, the ratio becomes
1.000068287 : 1
Which is close enough to 1:1 for me to consider the empirical formula to be CBr
Now calculate the molar mass of CBr
12.0107 + 79.904 = 91.9147
Finally, let's determine if the compound is actually CBr, or something like C2Br2, or some other multiple. Using the molar mass of CBr, multiply by the number of moles and see if the result matches the mass of the gas. So
91.9147 g/mol * 0.000464656 mol = 0.042708701 g
0.0427087 g is a lot smaller than 0.08541 g. So the compound isn't exactly CBr. Let's divide them to see what the factor is.
0.08541 / 0.0427087 = 1.99982673
1.99982673 is close enough to 2 to within the number of significant digits we have for me to claim that the formula for the unknown gas isn't CBr, but instead is C2Br2.</span>
Answer:
Mass percent N₂ = 89%
Mass percent H₂ = 11%
Explanation:
First we <u>use PV=nRT to calculate n</u>, which is the total number of moles of nitrogen and hydrogen:
- 1.03 atm * 7.45 L = n * 0.082 atm·L·mol⁻¹·K⁻¹ * 305 K
So now we know that
- MolH₂ + MolN₂ = 0.307 mol
and
- MolH₂ * 2 g/mol + MolN₂ * 28 g/mol = 3.49 g
So we have a <u>system of two equations and two unknowns</u>. We use algebra to solve it:
Express MolH₂ in terms of MolN₂:
- MolH₂ + MolN₂ = 0.307 mol
Replace that value in the second equation:
- MolH₂ * 2 g/mol + MolN₂ * 28 g/mol = 3.49
- (0.307-MolN₂) * 2 + MolN₂ * 28 = 3.49
- 0.614 - 2MolN₂ + 28molN₂ = 3.49
Now we calculate MolH₂:
- MolH₂ + MolN₂ = 0.307 mol
Finally, we convert each of those mol numbers to mass, to <u>calculate the mass percent</u>:
- N₂ ⇒ 0.111 mol * 28 g/mol = 3.108 g N₂
- H₂ ⇒ 0.196 mol * 2 g/mol = 0.392 g H₂
Mass % N₂ = 3.108/3.49 * 100% = 89.05% ≅ 89%
Mass % H₂ = 0.392/3.49 * 100% = 11.15% ≅ 11%
The
reaction is<span>
C</span>₂H₄ +
O₂ → CO₂ + H₂O<span>
To balance the equation, both side have same
number of elements. Here,</span>
In left hand
side has
in right hand side has
4 H atoms
2 H
atoms
2 C atoms 1 C
atom
<span>
2 O atoms 3 O
atoms
First, we have to balance number of C atoms and number of H atoms in both side.
To balance C atoms, '2' should be added before CO</span>₂ and to balance H atoms, '2' should be added
before H₂<span>O.
Then number of oxygen atoms is </span>2 x 2 + 2 = 6 in right hand side. So, 3 should be
added before O₂<span> in left hand side.
After balancing the equation should be,</span>
C₂H₄<span> + 3O</span>₂<span> → 2CO</span>₂<span> + 2H</span>₂O
