Answer: Rate law=
, order with respect to A is 1, order with respect to B is 2 and total order is 3. Rate law constant is 
Explanation: Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.
![Rate=k[A]^x[B]^y](https://tex.z-dn.net/?f=Rate%3Dk%5BA%5D%5Ex%5BB%5D%5Ey)
k= rate constant
x = order with respect to A
y = order with respect to A
n = x+y = Total order
a) From trial 1:
(1)
From trial 2:
(2)
Dividing 2 by 1 :![\frac{4.8\times 10^{-2}}{1.2\times 10^{-2}}=\frac{k[0.10]^x[0.40]^y}{k[0.10]^x[0.20]^y}](https://tex.z-dn.net/?f=%5Cfrac%7B4.8%5Ctimes%2010%5E%7B-2%7D%7D%7B1.2%5Ctimes%2010%5E%7B-2%7D%7D%3D%5Cfrac%7Bk%5B0.10%5D%5Ex%5B0.40%5D%5Ey%7D%7Bk%5B0.10%5D%5Ex%5B0.20%5D%5Ey%7D)
therefore y=2.
b) From trial 2:
(3)
From trial 3:
(4)
Dividing 4 by 3:![\frac{9.6\times 10^{-2}}{4.8\times 10^{-2}}=\frac{k[0.20]^x[0.40]^y}{k[0.10]^x[0.40]^y}](https://tex.z-dn.net/?f=%5Cfrac%7B9.6%5Ctimes%2010%5E%7B-2%7D%7D%7B4.8%5Ctimes%2010%5E%7B-2%7D%7D%3D%5Cfrac%7Bk%5B0.20%5D%5Ex%5B0.40%5D%5Ey%7D%7Bk%5B0.10%5D%5Ex%5B0.40%5D%5Ey%7D)
, x=1
Thus rate law is ![Rate=k[A]^1[B]^2](https://tex.z-dn.net/?f=Rate%3Dk%5BA%5D%5E1%5BB%5D%5E2)
Thus order with respect to A is 1 , order with respect to B is 2 and total order is 1+2=3.
c) For calculating k:
Using trial 1: ![1.2\times 10^{-2}=k[0.10]^1[0.20]^2](https://tex.z-dn.net/?f=1.2%5Ctimes%2010%5E%7B-2%7D%3Dk%5B0.10%5D%5E1%5B0.20%5D%5E2)
.
Answer:
0.0025moles
Explanation:
Molarity of a solution (M) = number of moles (n) ÷ volume (V)
According to this question, to make 250 mL of a 0.01 M solution of CaCl, the following number of moles is needed:
Volume = 250mL = 250/1000 = 0.250Litres.
Using; molarity = n/V
0.01 = n/0.250
n = 0.0025
n = 2.5 × 10^-3 moles.
– liquids, solids or gases – are made up of atoms and molecules that are in constant motion.<span> The theory also states that collisions between atoms and molecules are elastic</span>