What kind of bond is formed between a metal and a nonmetal? Explain your answer.
2 answers:
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Answer:
159 mg caffeine is being extracted in 60 mL dichloromethane
Explanation:
Given that:
mass of caffeine in 100 mL of water = 600 mg
Volume of the water = 100 mL
Partition co-efficient (K) = 4.6
mass of caffeine extracted = ??? (unknown)
The portion of the DCM = 60 mL
Partial co-efficient (K) =
where; solubility of compound in the organic solvent and
= solubility in aqueous water.
So; we can represent our data as:
÷
Since one part of the portion is A and the other part is B
A+B = 60 mL
A+B = 0.60
A= 0.60 - B
4.6= ÷
4.6 =
4.6 × =
4.6 B = 0.6 - B
2.76 B = 0.6 - B
2.76 + B = 0.6
3.76 B = 0.6
B =
B = 0.159 g
B = 159 mg
∴ 159 mg caffeine is being extracted from the 100 mL of water containing 600 mg of caffeine with one portion of in 60 mL dichloromethane.
Answer:The product formed on reaction with hydroxide ion as nucleophile is 2R-hexane-2-ol.
The product formed on reaction with water would be a 50:50 mixture of
2S-hexane-2-ol. and 2R-hexane-2-ol.
Explanation:
2S-iodohexane on reactiong with hydroxide ion would undergo SN² substitution reaction that is substitution bimolecular. Hydroxide ion has a negative charge and hence it is a quite good nucleophile .
The rate of a SN² reaction depends on both the substrate and nucleophile . Here the substrate is a secondary carbon center having Iodine as a leaving group.SN² reaction takes place here as hydroxide ion is a good nucleophile and it can attack the secondary carbon center from the back side leading to the formation of 2R-hexane-2-ol.
In a SN² reaction since the the nucleophile attacks from the back-side so the product formation takes place with the inversion of configuration.
When the same substrate S-2-iodohexane undergoes a substitution reaction with water as a nucleophile then the reaction occurs through (SN¹) substitution nucleophilic unimolecular mechanism .
The rate of a SN¹ reaction depends only on the nature of substrate and is independent of the nature of nucleophile.
The SN¹ reaction is a 2 step reaction , in the first step leaving group leaves leading to the formation of a carbocation and once the carbocation is formed then any weaker nucleophile or even solvent molecules can attack leading the formation of products.
In this case a secondary carbocation would be generated in the first step and then water will attack this carbocation to form the product in the second step.
The product formed on using water as a nucleophile would be a racemic mixture of R and S isomers of hexane -2-ol in 50:50 ratio. The two products formed would be 2R-hexane-2-ol and 2S-hexane-2-ol.
Kindly refer the attachment for reaction mechanism and structure of products.
