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3 years ago

15

As NaOH is added to an aqueous solution, the pH will 1. decrease. 2. Not enough information is given to solve the problem. 3. be

unaffected because NaOH is not an acid. 4. increase or decrease depending on whether the initial pH is higher or lower than 7. 5. increase

1 answer:

Dominik [7]3 years ago

4 0

PH increases when you add NaOH because it’s a strong base.

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Calculate E ° for the half‑reaction, AgCl ( s ) + e − − ⇀ ↽ − Ag ( s ) + Cl − ( aq ) given that the solubility product constant

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Answer: The value of $E^{o}$ for the half-cell reaction is 0.222 V.

Explanation:

Equation for solubility equilibrium is as follows.

$AgCl(s) \rightleftharpoons Ag^{+}(aq) + Cl^{-}(aq)$

Its solubility product will be as follows.

$K_{sp} = [Ag^{+}][Cl^{-}]$

Cell reaction for this equation is as follows.

$Ag(s)| AgCl(s)|Cl^{-}(0.1 M)|| Ag^{+}(1.0 M)| Ag(s)$

Reduction half-reaction: $Ag^{+} + 1e^{-} \rightarrow Ag(s)$ , $E^{o}_{Ag^{+}/Ag} = 0.799 V$

Oxidation half-reaction: $Ag(s) + Cl^{-}(aq) \rightarrow AgCl(s) + 1e^{-}$ , $E^{o}_{AgCl/Ag}$ = ?

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So, for this cell reaction the number of moles of electrons transferred are n = 1.

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Therefore, according to the Nernst equation

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$E_{cell} = E^{o}_{cell} - \frac{0.0592 V}{n} log \frac{[AgCl]}{[Ag^{+}][Cl^{-}]}$

$0.00 = E^{o}_{cell} - \frac{0.0592 V}{1} log \frac{1}{[Ag^{+}][Cl^{-}]}$

$E^{o}_{cell} = \frac{0.0592}{1} log \frac{1}{K_{sp}}$

= $0.0591 V \times log \frac{1}{1.77 \times 10^{-10}}$

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Hence, we will calculate the standard cell potential as follows.

$E^{o}_{cell} = E^{o}_{cathode} - E^{o}_{anode}$

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