<h3>
Answer:</h3>
14 milliliters
<h3>
Explanation:</h3>
We are given;
Prepared solution;
- Volume of solution as 0.350 L
- Molarity as 0.40 M
We are required to determine the initial volume of HNO₃
- We are going to use the dilution formula;
- The dilution formula is;
M₁V₁ = M₂V₂
Rearranging the formula;
V₁ = M₂V₂ ÷ M₁
=(0.40 M × 0.350 L) ÷ 10.0 M
= 0.014 L
But, 1 L = 1000 mL
Therefore,
Volume = 14 mL
Thus, the volume of 10.0 M HNO₃ is 14 mL
<u>Answer:</u>
<u>For A:</u> The
for the given reaction is 
<u>For B:</u> The
for the given reaction is 1642.
<u>Explanation:</u>
The given chemical reaction follows:

The expression of
for the above reaction follows:

We are given:

Putting values in above equation, we get:

Hence, the
for the given reaction is 
Relation of
with
is given by the formula:

where,
= equilibrium constant in terms of partial pressure = 
= equilibrium constant in terms of concentration = ?
R = Gas constant = 
T = temperature = 500 K
= change in number of moles of gas particles = 
Putting values in above equation, we get:

Hence, the
for the given reaction is 1642.
CH4 is <u>not</u> soluble in water
whereas CH3OH <u>is</u> soluble in water.
Answer:
A) t = 22.5 min and B) t = 29.94 min
Explanation:
Initial concentration, [A]₀ = 100
Final concentration = 100 -75 = 25
Time = 45 min
A) First order reaction
ln[A] − ln[A]₀ = −kt
Solving for k;
ln[25] − ln[100] = - 45k
-1.386 = -45k
k = 0.0308 min-1
How long after its start will the reaction be 50% complete?
Initial concentration, [A]₀ = 100
Final concentration, [A] = 100 -50 = 50
Time = ?
ln[A] − ln[A]₀ = −kt
Solving for k;
ln[50] − ln[100] = - 0.0308 * t
-0.693 = -0.0308 * t
t = 22.5 min
B) Zero Order
[A] = [A]₀ − kt
Using the values from the initial reaction and solving for k, we have;
25 = 100 - k(45)
-75 = -45k
k = 1.67 M min-1
How long after its start will the reaction be 50% complete?
Initial concentration, [A]₀ = 100
Final concentration, [A] = 100 -50 = 50
Time = ?
[A] = [A]₀ − kt
50 = 100 - (1.67)t
-50 = - 1.67t
t = 29.94 min
Chemical Equation Balancer