The last one, handmade gifts require more of the givers time!
Answer: ![-\frac{1}{2}\times \frac{d[Br^.]}{dt}=+\frac{d[Br_2]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7B1%7D%7B2%7D%5Ctimes%20%5Cfrac%7Bd%5BBr%5E.%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D)
Explanation:
Rate of a reaction is defined as the rate of change of concentration per unit time.
Thus for reaction:
The rate in terms of reactants is given as negative as the concentration of reactants is decreasing with time whereas the rate in terms of products is given as positive as the concentration of products is increasing with time.
![Rate=-\frac{d[Br^.]}{2dt}](https://tex.z-dn.net/?f=Rate%3D-%5Cfrac%7Bd%5BBr%5E.%5D%7D%7B2dt%7D)
or ![Rate=+\frac{d[Br_2]}{dt}](https://tex.z-dn.net/?f=Rate%3D%2B%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D)
Thus ![-\frac{d[Br^.]}{2dt}=+\frac{d[Br_2]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7Bd%5BBr%5E.%5D%7D%7B2dt%7D%3D%2B%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D)
This leads to a paradox known as the Gibbs paradox, after Josiah Willard Gibbs. The paradox allows for the entropy of closed systems to decrease, violating the second law of thermodynamics. A related paradox is the "mixing paradox".
Answer:
As the temperature of materials increase, the objects find a phenomenon called change of phase.
This means that if you give enough heat to a liquid, this can change of state from liquid state to gas state (the water evaporates)
So the water in the pan reaches the evaporation temperature (around 100°C) and it starts to evaporate, this is why the water on the outside begins to "dry"
