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3 years ago

Hund's rule states that electrons must spread out within a given subshell before they can pair

Chemistry

1 answer:

Temka [501]3 years ago

6 0

Answer:

Groups 14, 15, and 16 have 2,3, and 4 electrons in the p sublevel (p sublevel has 3 "spaces" AKA orbitals), because Hunds says one in each orbital before doubling up if you had 2 electrons, group 14, they would both be in the first orbital, with 3 electrons, group 15, two in the first orbital one in the 2nd none in the 3rd. With 4 electrons, group 16, then you would have 2 in the first 2 orbitals and NONE in the 3rd.

Explanation:

If you are in group 13 you only have 1 electron so it can only be in one orbital. with group 17, you have 5 electrons, so 2 in the first 2 in the second and 1 in the 3rd, correct for Hunds rule anyway. Noble gasses, group 18, have 6 elecctrons, so every orbital is full any way you look at it.

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The standard Gibbs energy of reaction, ÄG°, for the dissociation of phenol is 56.4 kJ mol-1 at 298 K. Calculate the pKa of pheno

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The decomposition of N2O5 in solution in carbon tetrachloride proceeds via the reaction 2 N2O5(soln) → 4 NO2(soln) + O2(soln) Th

Fantom [35]

Answer: The amount remained after 151 seconds are 0.041 moles

Explanation:

All the radioactive reactions follows first order kinetics.

Rate law expression for first order kinetics is given by the equation:

$k=\frac{2.303}{t}\log\frac{[A_o]}{[A]}$

where,

k = rate constant = $4.82\times 10^{-3}s^{-1}$

t = time taken for decay process = 151 sec

$[A_o]$ = initial amount of the reactant = 0.085 moles

[A] = amount left after decay process = ?

Putting values in above equation, we get:

$4.82\times 10^{-3}=\frac{2.303}{151}\log\frac{0.085}{[A]}$

$[A]=0.041moles$

Hence, the amount remained after 151 seconds are 0.041 moles

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4 years ago

If you mix 50mL of 0.1 M TRIS acid with 60 mL of0.2 M TRIS base, what will be the resulting pH?

Katyanochek1 [597]

Answer: The pH of resulting solution is 8.7

Explanation:

To calculate the number of moles for given molarity, we use the equation:

$\text{Molarity of the solution}=\frac{\text{Moles of solute}\times 1000}{\text{Volume of solution (in mL)}}$

For TRIS acid:

Molarity of TRIS acid solution = 0.1 M

Volume of solution = 50 mL

Putting values in above equation, we get:

$0.1M=\frac{\text{Moles of TRIS acid}\times 1000}{50mL}\\\\\text{Moles of TRIS acid}=0.005mol$

For TRIS base:

Molarity of TRIS base solution = 0.2 M

Volume of solution = 60 mL

Putting values in above equation, we get:

$0.2M=\frac{\text{Moles of TRIS base}\times 1000}{60mL}\\\\\text{Moles of TRIS base}=0.012mol$

Volume of solution = 50 + 60 = 110 mL = 0.11 L (Conversion factor: 1 L = 1000 mL)

To calculate the pH of acidic buffer, we use the equation given by Henderson Hasselbalch:

$pH=pK_a+\log(\frac{[salt]}{[acid]})$

$pH=pK_a+\log(\frac{[\text{TRIS base}]}{[\text{TRIS acid}]})$

We are given:

$pK_a$ = negative logarithm of acid dissociation constant of TRIS acid = 8.3

$[\text{TRIS acid}]=\frac{0.005}{0.11}$

$[\text{TRIS base}]=\frac{0.012}{0.11}$

pH = ?

Putting values in above equation, we get:

$pH=8.3+\log(\frac{0.012/0.11}{0.005/0.11})\\\\pH=8.7$

Hence, the pH of resulting solution is 8.7

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4 years ago

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