Answer:
c
Explanation:
c first quarter waxing half moon
<u>Ans: Acetic acid = 90.3 mM and Sodium acetate = 160 mM</u>
Given:
Acetic Acid/Sodium Acetate buffer of pH = 5.0
Let HA = acetic acid
A- = sodium acetate
Total concentration [HA] + [A-] = 250 mM ------(1)
pKa(acetic acid) = 4.75
Based on Henderson-Hasselbalch equation
pH = pKa + log[A-]/[HA]
[A-]/[HA] = 10^(pH-pKa) = 10^(5-4.75) = 10^0.25 = 1.77
[A-] = 1.77[HA] -----(2)
From (1) and (2)
[HA] + 1.77[HA] = 250 mM
[HA] = 250/2.77 = 90.25 mM
[A-] = 1.77(90.25) = 159.74 mM
Delta H of solution = -Lattice Energy + Hydration
<span>Delta H of solution=- (-730)+(-793) </span>
<span>Delta H of solution= -63kJ/mol </span>
<span>Now we find moles of LiI: </span>
<span>10gLiI/133.85g=.075moles </span>
<span>multiply moles to the delta H of solution to cross cancel moles. .75moles x -64kJ/mol =4.7</span>
