Answer : The pressure after the temperature change is, 0.752 atm
Explanation :
Gay-Lussac's Law : It is defined as the pressure of the gas is directly proportional to the temperature of the gas at constant volume and number of moles.

or,

where,
= initial pressure = 0.82 atm
= final pressure = ?
= initial temperature = 
= final temperature = 
Now put all the given values in the above equation, we get:


Thus, the pressure after the temperature change is, 0.752 atm
We have that the work function of the metal

From the Question we are told that
UV radiation (λ = 162 nm)
Kinetic energy 
Generally the equation for Kinetic energy is mathematically given as


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There are 11 Carbon atoms in the compound.
<u>Solution:</u>
Carbon atom count is the ratio of the M peak to the M+1 peak.

Here M peak is 57.10% and M+1 peak is 6.83%. On applying the values in the formula we get,

Therefore, the number of Carbon atoms in the compound are 11.
Refer the image attached below for a better understanding of M peak and M+1 peak.
The heaviest ion that has the greatest m/z value is said to be the molecular ion peak in mass spectrum.