Which of the following statements are part of the kinetic molecular theory ?
1 answer:
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<h3><u>Full Question:</u></h3>
The following compound has been found effective in treating pain and inflammation (J. Med. Chem. 2007, 4222). Which sequence correctly ranks each carbonyl group in order of increasing reactivity toward nucleophilic addition?
A) 1 < 2 < 3
B) 2 < 3 < 1
C) 3 < 1 < 2
D) 1 < 3 < 2
<h3><u>Answer: </u></h3>The rate of nucleophilic attack of carbonyl compounds is 2<3 <1.
Option B
<h3><u>Explanation. </u></h3>Nucleophilic attack is explained as the attack of an electron rich radical to a carbonyl compound like aldehyde or a ketone. A nucleophile has a high electron density, so it searches for a electropositive atom where it can donate a portion of its electron density and become stable.
A carbonyl compound is a hybridized carbon atom with a double bonded oxygen atom in it. The oxygen atom pulls a huge portion of electron density from carbon being very electropositive.
In a ketone, there are two factors that make it less likely to undergo a nucleophilic attack than aldehyde. Firstly, the steric hindrance of two carbon groups being attached with the carbonyl carbon makes it harder for the nucleophile to approach. Secondly, the electron push by the carbon groups attached makes the carbonyl carbon a bit less electropositive than the aldehyde one. So aldehydes are more reactive towards a nucleophilic addition reaction.
Answer:-
Water is highly ordered. In water each oxygen atom is connected to others around it through hydrogen bonding via bridging hydrogen atoms. When a salt like NaCl is dissolved, some of these Hydrogen bonds break.
When a salt like NaCl dissolves in water, the NaCl breaks in to ions Na+ and Cl-.
The water molecules now surround these ions.
The slightly negative oxygen end of water molecule gets near the Na+, while the slightly positive Hydrogen of water molecule gets near the Cl-.
So before salt sample dissolve, the water molecules were highly ordered due to hydrogen bonding. Now after salt dissolve there is a decrease in order and thus an increase in disorder of the water molecules.
Due to increase in disorder, entropy which is a measure of disorder increases. Since entropy increases, delta S for the process is positive.
