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emmainna [20.7K]
3 years ago
9

A) Find the gas speed of sulfur dioxide at 100.0 degrees Celsius? ______________

Chemistry
1 answer:
gtnhenbr [62]3 years ago
4 0

a. 381.27 m/s

b. the rate of effusion of sulfur dioxide = 2.5 faster than nitrogen triiodide

<h3>Further explanation</h3>

Given

T = 100 + 273 = 373 K

Required

a. the gas speedi

b. The rate of effusion comparison

Solution

a.

Average velocities of gases can be expressed as root-mean-square averages. (V rms)  

\large {\boxed {\bold {v_ {rms} = \sqrt {\dfrac {3RT} {Mm}}}}

R = gas constant, T = temperature, Mm = molar mass of the gas particles  

From the question  

R = 8,314 J / mol K  

T = temperature  

Mm = molar mass, kg / mol  

Molar mass of Sulfur dioxide = 64 g/mol = 0.064 kg/mol

\tt v=\sqrt{\dfrac{3\times 8.314\times 373}{0.064} }\\\\v=381.27~m/s

b. the effusion rates of two gases = the square root of the inverse of their molar masses:  

\rm \dfrac{r_1}{r_2}=\sqrt{\dfrac{M_2}{M_1} }

M₁ = molar mass sulfur dioxide = 64

M₂ =  molar mass nitrogen triodide = 395

\tt \dfrac{r_1}{r_2}=\sqrt{\dfrac{395}{64} }=\dfrac{20}{8}=2.5

the rate of effusion of sulfur dioxide = 2.5 faster than nitrogen triodide

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Answer: Concentration of CO = 0.328 M

Concentration of Cl_2 = 0.328 M

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Explanation:

Moles of  CO and Cl_2 = 0.430 mole

Volume of solution = 0.500 L

Initial concentration of CO and Cl_2  =\frac{moles}{volume}=\frac{0.430}{0.500}=0.860M

The given balanced equilibrium reaction is,

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Initial conc.          0.860M     0.860M           0

At eqm. conc.    (0.860-x) M  (0.860-x) M     (x) M

The expression for equilibrium constant for this reaction will be,

K_c=\frac{[COCl_2]}{[CO][Cl_2]}

Now put all the given values in this expression, we get :

4.95=\frac{x}{(0.860-x)^2}

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Concentration of CO = (0.860-x) M =(0.860-0.532) M = 0.328 M

Concentration of Cl_2 =  (0.860-x) M  =  (0.860-0.532) M = 0.328 M

Concentration of COCl_2 = x M = 0.532 M

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