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vodomira [7]
3 years ago
15

Aspirin that has been stored for a long time may give a vinegar like odour and give a purple colour with FeCl3. What reaction wo

uld cause this to happen
?.
Chemistry
1 answer:
iVinArrow [24]3 years ago
3 0

Answer:

See explanation

Explanation:

The IUPAC name of aspirin is 2-Acetoxybenzoic acid. It is composed of an acetoxy moiety and a benzoic acid moiety.

The compound can be hydrolysed under prolonged storage conditions to yield acetic acid which causes the vinegar like odour.

Also, one of the products of this hydrolysis bears a phenol group which reacts with FeCl3 to give a purple color.

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Answer:

6,78 mL of 12,0 wt% H₂SO₄

Explanation:

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H₂O (l) ⇄ H⁺ (aq) + OH⁻ (aq)

The initial concentration of [H⁺] is 10⁻⁸ M and final desired concentration is [H⁺] = 10^{-7,20}, thus,

Thus, you need to add:

[H⁺] = 10^{-7,2} -10^{-8,0} = 5,31x10⁻⁸ M

The total volume of the pool is:

9,00 m × 15,0 m ×2,50 m = 337,5 m³ ≡ 337500 L

Thus, moles of H⁺ you need to add are:

5,31x10⁻⁸ M × 337500 L = 1,792x10⁻² moles of H⁺

These moles comes from

H₂SO₄ → 2H⁺ +SO₄²⁻

Thus:

1,792x10⁻² moles of H⁺ × \frac{1H_{2}SO_4 mol}{2H^{+} mol} = 8,96x10⁻³ moles of H₂SO₄

These moles comes from:

8,96x10⁻³ moles of H₂SO₄ × \frac{98,1 g}{1 mol} × \frac{100 gSolution}{12 gH_{2}SO_4 } × \frac{1 mL}{1,080 g}  =

6,78 mL of 12,0wt% H₂SO₄

I hope it helps!

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