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Dovator [93]
3 years ago
5

calculate the standard potential arising from the reaction in which NADH is oxidized to NAD and the corresponding biological sta

ndard reaction Gibbs energy.
Chemistry
1 answer:
melisa1 [442]3 years ago
7 0

Answer:

-219.99kJ

Explanation:

The acronym '' NADH'' simply stands for what is known as coenzyme 1 with full meaning of Nicotinamide Adenine Dinucleotide Hydride. This substance is useful in the production of energy. The oxidation reaction of NADH causes it to produce NADP⁺ and the oxygen produces water when it is in the reduction process. The balanced equation for the oxidation reaction is given below as:

NADPH ---------------------------------------------------------------------> NADP⁺H⁺ + 2e⁻.

Also, the balanced equation for the reduction reaction is given below as:

\frac{1}{2} O₂ + 2H⁺ + 2e⁻ --------------------------------------------------------------> H₂O.

It can be shown from the above REDOX reaction that the total number of electrons getting transferred is 2.

The  Gibbs energy = -nFE. where n = 2, F = faraday's constant = 96485.3329 C and E = overall cell potential.

The overall cell potential = E[ reduction reaction] - E[oxidation reaction] = 0.82 - (- 0.32 ) = 1.14 V.

Hence, the Gibbs energy = - 2 × 96485.3329 × 1.14 = -219.99kJ

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1) The partial pressure of SO₂ gas in the larger container = 0.115 atm.

2) The partial pressure of N₂ gas in the larger container = 0.206 atm.

3) The total pressure in the vessel = 0.321 atm.

Explanation:

  • To calculate the partial pressure of each gas, we can use the general law of ideal gas: PV = nRT.

where, P is the partial pressure of the gas in atm,

V is the volume of the vessel in L,

n is the no. of moles of the gas,

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<u><em>1) What is the partial pressure of SO₂ gas in the larger container?</em></u>

<em>∵ P = nRT/V.</em>

n = mass/molar mass = (3.0 g)/(64.066 g/mol) = 0.047 mol.

R = 0.082 L.atm/mol.K.

T = 26 °C + 273.15 = 299.15 K.

V = 10.0 L. (The volume of the new container)

∴ P = nRT/V = (0.047 mol)(0.082 L.atm/mol.K)(299.15 K)/(10.0 L) = 0.115 atm.

<u><em>2) What is the partial pressure of N₂ gas in the larger container?</em></u>

<em>∵ P = nRT/V.</em>

n = mass/molar mass = (2.35 g)/(28.0 g/mol) = 0.084 mol.

R = 0.082 L.atm/mol.K.

T = 26 °C + 273.15 = 299.15 K.

V = 10.0 L. (The volume of the new container)

∴ P = nRT/V = (0.084 mol)(0.082 L.atm/mol.K)(299.15 K)/(10.0 L) = 0.206 atm.

<u><em>3) What is the total pressure in the vessel?</em></u>

  • According to Dalton's law the total pressure exerted is equal to the sum of the partial pressures of the individual gases.

<em>∵ The total pressure in the vessel = the partial pressure of SO₂ + the partial pressure of N₂.</em>

∴ The total pressure in the vessel = 0.115 + 0.206 = 0.321 atm.

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