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masya89 [10]
3 years ago
14

Choose the aqueous solution below with the highest freezing point. These are all solutions of nonvolatile solutes and you should

assume ideal van't Hoff factors where applicable.
(i) 0.200 m HOCH2CH2OH
(ii) 0.200 m Ba(NO3)2
(iii) 0.200 m K3PO3
(iv) 0.200 m Ca(CIO4)2
(v) These all have the same freezing point.
Chemistry
1 answer:
GrogVix [38]3 years ago
8 0

Answer:

0.200 m K3PO3

Explanation:

Let us remember that the freezing point depression is obtained from the formula;

ΔTf = Kf m i

Where;

Kf = freezing point constant

m = molality

i = Van't Hoff factor

The  Van't Hoff factor has to do with the number of particles in solution. Let us consider the  Van't Hoff factor for each specie.

0.200 m HOCH2CH2OH - 1

0.200 m Ba(NO3)2 - 3

0.200 m K3PO3 - 4

0.200 m Ca(CIO4)2 - 3

Hence, 0.200 m K3PO3 has the greatest van't Hoff factor and consequently the greatest freezing point depression.

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