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Vlad1618 [11]
3 years ago
14

For the following list of acids, rank the acids in strength from weakest acid to strongest acid.

Chemistry
1 answer:
-BARSIC- [3]3 years ago
6 0

Answer:

CH3OH < FCH2OH < F2CHOH < F3COH

Explanation:

Let us recall that, for a carboxylic acid, the dissociation of the acid yields;

RCOOH ⇄RCOO^- + H^+

The ease of dissociation and release of the hydrogen ion depends on the nature of the group designated R.

When R is is a highly electronegative element, the -I inductive effect causes the hydrogen to become less tightly held by the C-Cl bond.

As the number of electron withdrawing substituents increaseses, the acid ionizes much more and becomes stronger.CH3OH < FCH2OH < F2CHOH < F3COH

Hence, the order of decreasing acid strength is;

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2Al(s) + 3Cl₂(g) → 2AlCl₃(s)

Since it was stated that aluminum is in excess, this means that the amount of AlCl₃ produced will only depend on the amount of Cl₂ gas available. The molar mass of Cl₂ is 70.906 g/mol. Using stoichiometry, we have the following equation:

(21.0 g Cl₂/ 70.906 g/mol Cl₂) x 2 mol AlCl₃/ 2 mol Cl₂ = 0.1974 mol AlCl₃

Thus, we have determined that 0.1974 <span>moles of aluminum chloride can be produced from 21.0 g of chlorine gas. </span>
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The ideal gas heat capacity of nitrogen varies with temperature. It is given by:
hammer [34]

Answer:

A)  1059 J/mol

B)  17,920 J/mol

Explanation:

Given that:

Cp = 29.42 - (2.170*10^-3 ) T + (0.0582*10^-5 ) T2 + (1.305*10^-8 ) T3 – (0.823*10^-11) T4

R (constant) = 8.314

We know that:

C_p=C_v+R

We can determine C_v from above if we make C_v the subject of the formula as:

C_v=C_p-R

C_V = 29.42-(2.7*10^{-3})T+(5.82*10^{-7})T2-(1.305*10^{-8})T3-(8.23*10^{-12})T4-8.314

C_V = 21.106-(2.7*10^{-3})T+(5.82*10^{-7})T2-(1.305*10^{-8})T3-(8.23*10^{-12})T4

A).

The formula for calculating change in internal energy is given as:

dU=C_vdT

If we integrate above data into the equation; it implies that:

U2-U1=\int\limits^{500}_{450}(21.106-(2.7*10^{-3})T+(5.82*10^{-7})T2-(1.305*10^{-8})T3-(8.23*10^{-12})T4\,) du

U2-U1=\int\limits^{500}_{450}(21.106-(2.7*10^{-3})T/1+(5.82*10^{-7})T2/2-(1.305*10^{-8})T3/3-(8.23*10^{-12})T4/4\,)

U2-U1= 1059J/mol

Hence, the internal energy that must be added to nitrogen in order to increase its temperature from 450 to 500 K = 1059 J/mol.

B).

If we repeat part A for an initial temperature of 273 K and final temperature of 1073 K.

then T = 273 K & T2 = 1073 K

∴

U2-U1=\int\limits^{500}_{450}(21.106-(2.7*10^{-3})T/1+(5.82*10^{-7})T2/2-(1.305*10^{-8})T3/3-(8.23*10^{-12})T4/4\,)

U2-U1=\int\limits^{500}_{450}(21.106-(2.7*10^{-3})273/1+(5.82*10^{-7})1073/2-(1.305*10^{-8})T3/3-(8.23*10^{-12})T4/4\,)

U2-U1= 17,920 J/mol

3 0
4 years ago
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