A chemical engineer must calculate the maximum safe operating temperature of a high-pressure gas reaction vessel. The vessel is
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Consider the isomerization of butane with equilibrium constant is 2.5 .The system is originally at equilibrium with :
[butane]=1.0 M , [isobutane]=2.5 M
If 0.50 mol/L of butane is added to the original equilibrium mixture and the system shifts to a new equilibrium position, what is the equilibrium concentration of each gas?
Answer:
The equilibrium concentration of each gas:
[Butane] = 1.14 M
[isobutane] = 2.86 M
Explanation:
Butane ⇄ Isobutane
At equilibrium
1.0 M 2.5 M
After addition of 0.50 M of butane:
(1.0 + 0.50) M -
After equilibrium reestablishes:
(1.50-x)M (2.5+x)
The equilibrium expression will wriiten as:
x = 0.36 M
The equilibrium concentration of each gas:
[Butane]= (1.50-x) = 1.50 M - 0.36M = 1.14 M
[isobutane]= (2.5+x) = 2.50 M + 0.36 M = 2.86 M