M(NH₃)=51g, n(NH₃)=m/M=51g÷17g/mol(14+3×1)=3mol
N(NH₃)=n×Na(Avogadro number)=3mol×6·10²³1/mol=18×10²³ molecules
Balanced chemical reaction: 2CH₄(g) ⇄ C₂H₂(g) + 3H₂(g).
1) In a chemical reaction, chemical equilibrium is the state in which both reactants (methane CH₄) and products (ethyne C₂H₂ and hydrogen H₂) are present in concentrations which have no further tendency to change with time.
2) At equilibrium, both the forward and reverse reactions are still occurring.
3) Reaction rates of the forward and backward reactions are equal and there are no changes in the concentrations of the reactants and products.
Answer:
At 430.34 K the reaction will be at equilibrium, at T > 430.34 the
reaction will be spontaneous, and at T < 430.4K the reaction will not
occur spontaneously.
Explanation:
1) Variables:
G = Gibbs energy
H = enthalpy
S = entropy
2) Formula (definition)
G = H + TS
=> ΔG = ΔH - TΔS
3) conditions
ΔG < 0 => spontaneous reaction
ΔG = 0 => equilibrium
ΔG > 0 non espontaneous reaction
4) Assuming the data given correspond to ΔH and ΔS
ΔG = ΔH - T ΔS = 62.4 kJ/mol + T 0.145 kJ / mol * K
=> T = [ΔH - ΔG] / ΔS
ΔG = 0 => T = [ 62.4 kJ/mol - 0 ] / 0.145 kJ/mol*K = 430.34K
This is, at 430.34 K the reaction will be at equilibrium, at T > 430.34 the reaction will be spontaneous, and at T < 430.4K the reaction will not occur spontaneously.
