Answer:
ΔG°rxn = +50.8 kJ/mol
Explanation:
It is possible to obtain ΔG°rxn of a reaction at certain temperature from ΔH°rxn and S°rxn, thus:
<em>ΔG°rxn = ΔH°rxn - T×S°rxn (1)</em>
In the reaction:
2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l)
ΔH°rxn = 3×ΔHfNO2 + ΔHfH2O - (2×ΔHfHNO3 + ΔHfNO)
ΔH°rxn = 3×33.2kJ/mol + (-285.8kJ/mol) - (2×-207.0kJ/mol + 91.3kJ/mol)}
ΔH°rxn = 136.5kJ/mol
And S°:
S°rxn = 3×S°NO2 + S°H2O - (2×S°HNO3 + S°NO)
ΔH°rxn = 3×0.2401kJ/molK + (0.0700kJ/molK) - (2×0.146kJ/molK + 0.2108kJ/molK)
ΔH°rxn = 0.2875kJ/molK
And replacing in (1) at 298K:
ΔG°rxn = 136.5kJ/mol - 298K×0.2875kJ/molK
<em>ΔG°rxn = +50.8 kJ/mol</em>
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Answer:
.
Explanation:
Electrons are conserved in a chemical equation.
The superscript of
indicates that each of these ions carries a charge of
. That corresponds to the shortage of one electron for each
ion.
Similarly, the superscript
on each
ion indicates a shortage of three electrons per such ion.
Assume that the coefficient of
(among the reactants) is
, and that the coefficient of
(among the reactants) is
.
.
There would thus be
silver (
) atoms and
aluminum (
) atoms on either side of the equation. Hence, the coefficient for
and
would be
and
, respectively.
.
The
ions on the left-hand side of the equation would correspond to the shortage of
electrons. On the other hand, the
ions on the right-hand side of this equation would correspond to the shortage of
electrons.
Just like atoms, electrons are also conserved in a chemical reaction. Therefore, if the left-hand side has a shortage of
electrons, the right-hand side should also be
electrons short of being neutral. On the other hand, it is already shown that the right-hand side would have a shortage of
electrons. These two expressions should have the same value. Therefore,
.
The smallest integer
and
that could satisfy this relation are
and
. The equation becomes:
.
Because potassium is a gas that can evolve