Answer:-
Water is highly ordered. In water each oxygen atom is connected to others around it through hydrogen bonding via bridging hydrogen atoms. When a salt like NaCl is dissolved, some of these Hydrogen bonds break.
When a salt like NaCl dissolves in water, the NaCl breaks in to ions Na+ and Cl-.
The water molecules now surround these ions.
The slightly negative oxygen end of water molecule gets near the Na+, while the slightly positive Hydrogen of water molecule gets near the Cl-.
So before salt sample dissolve, the water molecules were highly ordered due to hydrogen bonding. Now after salt dissolve there is a decrease in order and thus an increase in disorder of the water molecules.
Due to increase in disorder, entropy which is a measure of disorder increases. Since entropy increases, delta S for the process is positive.
Answer:
N,N-dimethylacetamide is formed.
Explanation:
- It is an example of a nucleophilic addition-elimination reaction. Here dimethylamine acts as a nucleophile.
- In the first step, dimethyl amine gives nucleophilic addition reaction at carbonyl center of acetyl chloride.
- In the second step, removal of Cl atoms occurs.
- In the third step, deprotonation takes place from amino group to produce N,N-dimethylacetamide.
- Full reaction mechanism has been shown below.
Answer:
Explanation:
Butane is an alkane and has no multiple bond in it.
The isomers of butane are
a) n-butane
b) t-butane
The structures are shown in the figure.
The most stable radical will be tertiary butyl radical.
The structures are shown in figure.
Answer:
Hg(NO₃)₂(aq) + Na₂SO₄(aq) → 2NaNO₃(aq) + HgSO₄(s)
Moles of Hg(NO₃)₂ = 55.42 / 324.7 ==> 0.1707 moles
Moles of Na₂SO₄ = 16.642 / 142.04 ==> 0.1172 moles
Limiting reagent is Na₂SO₄ as it controls product formation
Moles of HgSO₄ formed = 0.1172 moles
= 0.1172 x 296.65
= 34.757g
Explanation: