Answer:
1. HBr>HCl> H2S >BH3
2.K_a1 very large — H2SO4
K_a1= 1.7 x 10^−2 — H2SO3
K_a1 = 1.7 x 10^−7 — H2S
Explanation:
As one goes down a row in the Periodic Table the properties that determine the acid strength can be observed.
The atoms get larger in radius meaning that in strength, the strength of the bonds get weaker, conversely meaning that the acids get stronger.
For the halogen-containing acids above following the rows and periods, HBr has the strongest bond and is the strongest acid and others follow in this order.
HBr>HCl> H2S >BH3
Acid Dissociation Constant provides us with information known as the ionization constant which comes in handy to measure the acid's strength. The meaning of the proportions are thus, the higher the Ka value, the stronger the acid i.e. it liberates more number of hydrogen ions per mole of acid in solution.
In solution strong acids completely dissociate hence, the value of dissociation constant of strong acids is very high.
Following the cues above on Ka;
K_a1 very large — H2SO4
K_a1= 1.7 x 10^−2 — H2SO3
K_a1 = 1.7 x 10^−7 — H2S
Answer:
NH3 has greater water solubility due to intermoleculate interactions
Explanation:
Hi:
If we represent the structures of NH3 and SbH3 we can see that they are similar to the naked eye, this is because N and Sb belong to the same group of the periodic table (group 15).
However, the electronegativity of N is greater than that of Sb. The NH3 molecule is polar and can form an intermolecular interaction called hydrogen bridge with water.
Sb is less electronegative than N. The SBH3 molecule forms an intermolecular interaction with water called dipole-induced dipole.
The zone with positive charge density of the water molecule (hydrogens) is oriented towards the zone with positive charge density of SBH3 (the pair of electrons not shared)
Stronger intermolecular junctions allow greater solubility of NH3 molecules.
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