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3 years ago

A solution of which of the following coordination compounds will form a precipitate when treated with aqueous AgNO3?

Chemistry

1 answer:

lidiya [134]3 years ago

3 0

Answer:

[Cr(NH3)6.]C13

Explanation:

Alfred Werner's coordination theory (1893) recognized two kinds of valency;

Primary valency which are nondirectional and secondary valency which are directional.

Hence, the number of counter ions precipitated from a complex depends on the primary valency of the central metal ion in the complex.

We must note that it is only these counter ions that occur outside the coordination sphere that can be precipitated by AgNO3.

If we consider the options carefully, only [Cr(NH3)6.]C13 possess counter ions outside the coordination sphere which can be precipitated when treated with aqueous AgNO3.

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The molar mass for PCL3 is 137.33 g/mol

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Why atomic mass is an average vàlue

lukranit [14]

Answer:

The atomic mass is the average number of protons and neutrons for all natural isotopes of an element. It is a decimal number.

Explanation:

Atomic Mass and Mass Number Example :

Hydrogen has three natural isotopes: 1H, 2H, and 3H. Each isotope has a different mass number.

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3 years ago

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A mysterious white powder could be powdered sugar (C12H22O11), cocaine (C17H21NO4), codeine (C18H21NO3), norfenefrine (C8H11NO2)

rodikova [14]

Norfenefrine (C₈H₁₁NO₂).

<h3>Further explanation</h3>

We will solve a case related to one of the colligative properties, namely freezing point depression.

The freezing point of the solution is the temperature at which the solution begins to freeze. The difference between the freezing point of the solvent and the freezing point of the solution is called freezing point depression.

$\boxed{ \ \Delta T_f = T_f(solvent) - T_f(solution) \ } \rightarrow \boxed{ \ \Delta T_f = K_f \times molality \ }$

<u>Given:</u>

A mysterious white powder could be,

powdered sugar (C₁₂H₂₂O₁₁) with a molar mass of 342.30 g/moles,
cocaine (C₁₇H₂₁NO₄) with a molar mass of 303.35 g/moles,
codeine (C₁₈H₂₁NO₃) with a molar mass of 299.36 g/moles,
norfenefrine (C₈H₁₁NO₂) with a molar mass of 153.18 g/moles, or
fructose (C₆H₁₂O₆) with a molar mass of 180.16 g/moles.

When 82 mg of the powder is dissolved in 1.50 mL of ethanol (density = 0.789 g/cm³, normal freezing point −114.6°C, Kf = 1.99°C/m), the freezing point is lowered to −115.5°C.

<u>Question: </u>What is the identity of the white powder?

<u>The Process:</u>

Let us identify the solute, the solvent, initial, and final temperatures.

The solute = the powder
The solvent = ethanol
The freezing point of the solvent = −114.6°C
The freezing point of the solution = −115.5°C

Prepare masses of solutes and solvents.

Mass of solute = 82 mg = 0.082 g
Mass of solvent = density x volume, i.e., $\boxed{ \ 0.789 \ \frac{g}{cm^3} \times 1.50 \ cm^3 = 1.1835 \ g = 0.00118 \ kg \ }$

We must prepare the solvent mass unit in kg because the unit of molality is the mole of the solute divided by the mass of the solvent in kg.

The molality formula is as follows:

$\boxed{ \ m = \frac{moles \ of \ solute}{kg \ of \ solvent} \ } \rightarrow \boxed{ \ m = \frac{mass \ of \ solute \ (g)}{molar \ mass \ of \ solute \times kg \ of \ solvent} \ }$

Now we combine it with the formula of freezing point depression.

$\boxed{ \ \Delta T_f = K_f \times \frac{mass \ of \ solute \ (g)}{molar \ mass \ of \ solute \times kg \ of \ solvent} \ }$

It is clear that we will determine the molar mass of the solute (denoted by Mr).

We enter all data into the formula.

$\boxed{ \ -114.6^0C - (-115.5^0C) = 1.99 \frac{^0C}{m} \times \frac{0.082 \ g}{Mr \times 0.00118 \ kg} \ }$

$\boxed{ \ 0.9 = \frac{1.99 \times 0.082}{Mr \times 0.00118} \ }$

$\boxed{ \ Mr = \frac{0.16318}{0.9 \times 0.00118} \ }$

We get $\boxed{ \ Mr = 153.65 \ }$

These results are very close to the molar mass of norfenefrine which is 153.18 g/mol. Thus the white powder is norfenefrine.

<h3>Learn more</h3>

The molality and mole fraction of water brainly.com/question/10861444
About the mass and density of ethylene glycol as an antifreeze brainly.com/question/4053884
About the solution as a homogeneous mixture brainly.com/question/637791

Keywords: a mysterious white powder, sugar, cocaine, codeine, norfenefrine, fructose, the solute, the solvent, dissolved, ethanol, normal freezing point, the freezing point depression, the identity

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3 years ago

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3 years ago

A sample of 3.62 moles of diphosphorous trioxide is

Sindrei [870]

$H_3PO_3$ $2H_3PO_3$ $2H_3PO_3$ $P_2O_3$ Answer:

Explanation:

This question is about stoichiometry. From the balanced equation $P_2O_3 + 3H_2O$ ⇒ $2H_3PO_3$ , we see that 3 moles of water is needed to react with 1 mole of $P_2O_3$ .

This means that, to fully react 3.62 moles of $P_2O_3$ , we would need 3*3.62 or 10.86 moles of water. However, we only have 6.31 moles, so water is the limiting reactant.

Since 3 moles of water react with 1 mole of $P_2O_3$ , 6.31 moles of water can fully react with 6.31÷3 or 2.1033 moles of $P_2O_3$ .

From the balanced equation, we see that every mole of $P_2O_3$ reacted gets you 2 moles of $2H_3PO_3$ . Therefore, 2.1033 moles of $P_2O_3$ would give you approximately 4.21 moles of $H_3PO_3$ .

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2 years ago