Answer:
Well, carbon monoxide can be created from formic acid by adding sulphuric acid which will dehydrate said formic acid:
HCOOH
−
→
−
−
−
H
2
SO
4
CO+H
2
O
HCOOH→HX2SOX4CO+HX2O
Therefore, we can imagine the reverse reaction theoretically, which would make carbon monoxide an acidic oxide. However, the forward reaction does not proceed easily and it needs both the high acidity of sulphuric acid and its strong dehydrative properties to actually work. And your question mentions using hot, concentrated sodium hydroxide to make the reverse one work.
Most oxides that are classified as acidic or basic either have a very electrophilic central atom (e.g.
CO
2
COX2
) which can be attacked by the weak nucleophile water (which in turn can then release an acidic proton), or they have a high charge density on the oxygen which allows it to abstract a proton from water directly. Carbon monoxide is neither. If you check out its molecular orbitals, you will notice that even though carbon is partially positive it has the largest HOMO contribution, meaning a proton would be more likely to attatch to the carbon side — which doesn’t want one at all. The LUMO is, luckily, also more carbon-centred, meaning nucleophilic attacks on carbon are possible. However, it is also degenerate due to the double bond so that an attack is not favoured.
Thus, the carbon monoxide molecule is one that won’t react with water at all and totally defies the concept of acidic/basic oxides.
Abbreviations:
HOMO is a widely used abbreviation for the Highest Occupied Molecular Orbital, i.e. the one with the highest energy that still contains electrons. It is usually the orbital that will attack nucleophilicly or that will be attacked electrophilicly.
LUMO is a widely used abbreviation for the Lowest Unoccupied Molecular Orbital, i.e. the virtual (unoccupied) orbital that has the lowest energy. When considering a nucleophilic attack, the attacking electrons will usually interact with the LUMO. Electrophiles attack with other molecules’ HOMO with their LUMO.
Explanation:
Less dense because there mainly gas
ANSWER: From this experiment, Jeff can conclude that the heat capacity of oil is lower than that of water which means that oil requires less energy per gram of liquid in order to change its temperature.
Acid rain slowly dissolves rocks due to chemical reactions between the acid and the minerals in the rock. Differential Weathering: Softer, less resistant rocks wear away at a faster rate than more weather resistant rocks. More exposure to acid rain results in more rapid weathering.
Answer:
5 significant figures
Explanation:
- Zeros that come before any non-zero digits are never significant.
- Zeros that are in between any non-zero digits are always significant.
- Zeros that come after any non-zero digit are ONLY significant if a decimal point in present somewhere in the number. (In this case there is a decimal point, but there aren't any zeros at the end of this number.)
I have underlined the significant figures in this number:
<u>3</u> <u>8</u> <u>5</u> . <u>0</u> <u>1</u>
