Lower flammable limit means the lowest concentration of a material that will propagate a flame.
What is hazardous atmosphere?
It is an atmosphere that may expose employees to risk of death, incapacitation, impairment of ability to self-rescue, injury, or acute illness from one or more of following causes
- Flammable gas, vapor, or mist in excess of 10 percent of lower flammable limit (LFL)
- Airborne combustible dust at concentration that meets or exceeds its LFL
What is lower flammable limit?
- It means the lowest concentration of a material that will propagate a flame.
- The LFL is usually expressed as percent by volume of material in air (or other oxidant)
- Atmospheres with concentration of flammable vapors at or above 10 percent of lower explosive limit (LEL) are considered hazardous when located in confined spaces.
- However, atmospheres with flammable vapors below 10 percent of LEL are not necessarily safe. Such atmospheres are too lean to burn
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C Linnaeus was the first person known to have used the terms genus and species when classifying organisms.
The correct option is (b)
NaNH2 is an effective base. It can be a good nucleophile in the few situations where its strong basicity does not have negative side effects. It is employed in elimination reactions as well as the deprotonation of weak acids.Alkynes, alcohols, and a variety of other functional groups with acidic protons, such as esters and ketones, will all be deprotonated by NaNH2, a powerful base.Alkynes are deprotonated with NaNH2 to produce what are known as "acetylide" ions. These ions are powerful nucleophiles that can react with alkyl halides to create carbon-carbon bonds and add to carbonyls in an addition reaction.Acid/base and nucleophilic substitution are the two types of reactions.Using the right base, terminal alkynes can be deprotonated to produce a carbanion.A good C is the acetylide carbanion.The acetylide carbanion can undergo nucleophilic substitution reactions because it is a potent C nucleophile. (often SN2) with 1 or 2 alkyl halides with electrophilic C to create an internal alkyne (Cl, Br, or I).Elimination is more likely to occur with 3-alkyl halides.It is possible to swap either one or both of the terminal H atoms in ethylene (acetylene) to create monosubstituted (R-C-C-H) and symmetrical (R = R') or unsymmetrical (R not equal to R') disubstituted alkynes (R-C-C-R').
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<span>Charles' law says "at a constant pressure, the volume of a fixed amount of gas is directly proportional to its absolute temperature".
V </span>α T
Where V is the volume and T is the temperature in Kelvin of the gas. We can use this for two situations as,
V₁/T₁ = V₂/T₂
V₁ = 2.00 L
T₁ = 40.0 ⁰C = 313 K
V₂ = ?
T₂ = 30.0 ⁰C = 303 K
By applying the formula,
2.00 L / 313 K = V₂ / 303 K
V₂ = (2.00 L / 313 K) x 303 K
V₂ = 1.94 L
Hence, the volume of the balloon at 30.0 ⁰C is 1.94 L