Answer:
C) In[reactant] vs. time
Explanation:
For a first order reaction the integrated rate law equation is:
where A(0) = initial concentration of the reactant
A = concentration after time 't'
k = rate constant
Taking ln on both sides gives:
![ln[A] = ln[A]_{0}-kt](https://tex.z-dn.net/?f=ln%5BA%5D%20%3D%20ln%5BA%5D_%7B0%7D-kt)
Therefore a plot of ln[A] vs t should give a straight line with a slope = -k
Hence, ln[reactant] vs time should be plotted for a first order reaction.
Two German chemists, Justus von Liebig (1803–1873) and Friedrich Wöhler (1800–1882), were responsible for the emergence of organic chemistry in the early nineteenth century. Their quantitative analytical methods helped establish the constitution of newly isolated and synthesized carbon compounds.
Answer: The enthalpy change for formation of butane is -125 kJ/mol
Explanation:
The balanced chemical reaction is,
The expression for enthalpy change is,
![\Delta H=[n\times H_f{products}]-[n\times H_f{reactants}]](https://tex.z-dn.net/?f=%5CDelta%20H%3D%5Bn%5Ctimes%20H_f%7Bproducts%7D%5D-%5Bn%5Ctimes%20H_f%7Breactants%7D%5D)
Putting the values we get :
![\Delta H=[4\times H_f_{CO_2}+5\times H_f_{H_2O}]-[1\times H_f_{C_4H_{10}}+\frac{13}{2}\times H_f_{O_2}]](https://tex.z-dn.net/?f=%5CDelta%20H%3D%5B4%5Ctimes%20H_f_%7BCO_2%7D%2B5%5Ctimes%20H_f_%7BH_2O%7D%5D-%5B1%5Ctimes%20H_f_%7BC_4H_%7B10%7D%7D%2B%5Cfrac%7B13%7D%7B2%7D%5Ctimes%20H_f_%7BO_2%7D%5D)
![-2877=[(4\times -393)+(5\times -286)]-[1\times H_f_{C_4H_{10}}+\frac{13}{2}\times 0]](https://tex.z-dn.net/?f=-2877%3D%5B%284%5Ctimes%20-393%29%2B%285%5Ctimes%20-286%29%5D-%5B1%5Ctimes%20H_f_%7BC_4H_%7B10%7D%7D%2B%5Cfrac%7B13%7D%7B2%7D%5Ctimes%200%5D)
Thus enthalpy change for formation of butane is -125 kJ/mol
Answer:
49.86 × 10²³ atoms of Al
Explanation:
Given data:
Number of moles of Al = 8.28 mol
Number of atoms = ?
Solution:
The given problem will solve by using Avogadro number.
It is the number of atoms , ions and molecules in one gram atom of element, one gram molecules of compound and one gram ions of a substance.
The number 6.022 × 10²³ is called Avogadro number.
For example,
18 g of water = 1 mole = 6.022 × 10²³ molecules of water
1.008 g of hydrogen = 1 mole = 6.022 × 10²³ atoms of hydrogen
For 8.28 moles of Al:
1 mole = 6.022 × 10²³ atoms of Al
8.28 mol×6.022 × 10²³ atoms / 1mol
49.86 × 10²³ atoms of Al
