Answer:
Explained below.
Explanation:
A substance at low temperature simply means that the average energy of molecular motion in that substance is low while at higher temperature, the average energy of molecular ml tip in that substance is high.
To calculate the <span>δ h, we must balance first the reaction:
NO + 0.5O2 -----> NO2
Then we write all the reactions,
2O3 -----> 3O2 </span><span>δ h = -426 kj eq. (1)
O2 -----> 2O </span><span>δ h = 490 kj eq. (2)
NO + O3 -----> NO2 + O2 </span><span>δ h = -200 kj eq. (3)
We divide eq. (1) by 2, we get
</span>O3 -----> 1.5O2 δ h = -213 kj eq. (4)
Then, we subtract eq. (3) by eq. (4)
NO + O3 -----> NO2 + O2 δ h = -200 kj
- (O3 -----> 1.5 O2 δ h = -213 kj)
NO -----> NO2 - 0.5O2 δ h = 13 kj eq. (5)
eq. (2) divided by -2. (Note: Dividing or multiplying by negative number reverses the reaction)
O -----> 0.5O2 <span>δ h = -245 kj eq. (6)
</span>
Add eq. (6) to eq. (5), we get
NO -----> NO2 - 0.5O2 δ h = 13 kj
+ O -----> 0.5O2 δ h = -245 kj
NO + O ----> NO2 δ h = -232 kj
<em>ANSWER:</em> <em>NO + O ----> NO2 δ h = -232 kj</em>
According to markovnikov's rule of the electrophilic addition to an alkene, the electrophile, usually a proton, is more likely to add to the less-substituted carbon in a double bond.
With additional substituents present in this configuration, the intermediate carbocation is stabilised by being located on the more-substituted carbon.
The nucleophile will then end up in a double bond on the more-substituted carbon in a reaction that follows Markovnikov's rule.The outcome of some addition reactions is described by Markovnikov's rule or Markownikoff's rule in organic chemistry. Vladimir Markovnikov, a Russian scientist, created the rule in 1870.
To learn more about Markovnikov's rule
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Explanation:
Lithium diisopropylamide (LDA) is used in many organic synthesis and is a strong base. It is prepared by the acid base reaction of N,N-diisopropylamine ( [(CH₃)₂CH]₂NH ) and butyllithium ( Li⁺⁻CH₂CH₂CH₂CH₃ ).
The equation is show below as:
[(CH₃)₂CH]₂NH + Li⁺⁻CH₂CH₂CH₂CH₃ ⇒ [(CH₃)₂CH]₂N⁻Li⁺ + CH₃CH₂CH₂CH₃
N,N-diisopropylamine ( [(CH₃)₂CH]₂NH ) is a weaker acid and hence, LDA ( [(CH₃)₂CH]₂N⁻Li⁺ ) is stronger base. (Weaker acid has stronger conjugate base)
Butyllithium ( Li⁺⁻CH₂CH₂CH₂CH₃ ) is a very strong base and hence, butane ( CH₃CH₂CH₂CH₃ ) is a very weak acid. (Strong base has weaker conjugate acid)
<span>No, this is not possible. The reason for this impossibility is that the electrons are not attracted to one another, and thus, would repel. If you were to push the atoms into each other, the electrons would then prevent this from happening. Essentially atoms will bounce off of one another due to the repel of charges.</span>