Which best describes the structure of 2-butene
2 answers:
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The compounds can react with OH⁻ and HCO₃⁻ only C₅H₆N pyridinium
<h3><em>Further explanation </em></h3>In an acid-base reaction, it can be determined whether or not a reaction occurs by knowing the value of pKa or Ka from acid and conjugate acid (acid from the reaction)
Acids and bases according to Bronsted-Lowry
Acid = donor (donor) proton (H + ion)
Base = proton (receiver) acceptor (H + ion)
If the acid gives (H +), then the remaining acid is a conjugate base because it accepts protons. Conversely, if a base receives (H +), then the base formed can release protons and is called the conjugate acid from the original base.
From this, it can be seen whether the acid in the product can give its proton to a base (or acid which has a lower Ka value) so that the reaction can go to the right to produce the product.
The step that needs to be done is to know the pKa value of the two acids (one on the left side and one on the right side of the arrow), then just determine the value of the equilibrium constant
Can be formulated:
K acid-base reaction = Ka acid on the left : K acid on the right.
or:
pK = acid pKa on the left - pKa acid on the right
K = equilibrium constant for acid-base reactions
pK = -log K;
K value> 1 indicates the reaction can take place, or the position of equilibrium to the right.
There is some data that we need to complete from the problem above, which is the pKa value of some compounds that will react, namely:
pyridinium pKa = 5.25
acetone pKa = 19.3
butan-2-one pKa = 19
Let's look at the K value of each possible reaction:
pka H₂O = 15.74, pka of H₂CO₃ = 6.37)
- 1. C₅H₆N pyridinium
* with OH⁻
C₅H₆N + OH- ---> C₅H₅N- + H₂O
pK = pKa pyridinium - pKa H₂O
pK = 5.25 - 15.74
pK = -10.49
K values> 1 indicate the reaction can take place
* with HCO3⁻
C₅H₆N + HCO₃⁻-- ---> C₅H₅N⁻ + H₂CO₃
pK = 5.25 - 6.37
pK = -1.12
Reaction can take place
- 2. Acetone C₃H₆O
* with OH-
C₃H₆O + OH⁻ ---> C₃H₅O- + H₂O
pK = 19.3 - 15.74
pK = 3.56
Reaction does not happen
* with HCO₃-
C₃H₆O + HCO₃⁻ ----> C₃H₅O⁻ + H₂CO₃
pK = 19.3 - 6.37
pK = 12.93
Reaction does not happen
- 3. butan-2-one C₄H₇O
* with OH-
C₄H₇O + OH- ---> C₄H₆O- + H₂O
pK = 19 - 15.74
pK = 3.26
Reaction does not happen
* with HCO₃⁻
C₄H₇O + HCO₃⁻ ---> C₄H₆O⁻ + H₂CO₃
pK = 19 - 6.37
pK = 12.63
Reaction does not happen
So that can react with OH⁻ and HCO₃⁻ only C₅H₆N pyridinium
<h3><em>Learn more </em></h3>
the lowest ph
the concentrations at equilibrium.
the ph of a solution
Keywords : acid base reaction, the equilibrium constant
Taking into account the reaction stoichiometry, P₄ will be the limiting reagent.
<h3>Reaction stoichiometry</h3>In first place, the balanced reaction is:
8 P₄ + 3 S₈ → 8 P₄S₃
By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:
- P₄: 8 moles
- S₈: 3 moles
- P₄S₃: 8 moles
The limiting reagent is one that is consumed first in its entirety, determining the amount of product in the reaction. When the limiting reagent is finished, the chemical reaction will stop.
<h3>Limiting reagent in this case</h3>To determine the limiting reagent, it is possible to use a simple rule of three as follows: if by stoichiometry 3 moles of S₈ reacts with 8 moles of P₄, 4 moles of S₈ reacts with how many moles of P₄?
<u><em>moles of P₄= 10.667 moles</em></u>
But 10.667 moles of P₄ are not available, 4 moles are available. Since you have less amount of moles than you need to react with 4 moles of S₈, P₄ will be the limiting reagent.
Learn more about the reaction stoichiometry:
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