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hjlf
3 years ago
8

Calculate the volume of one mole of a gas at 1.00 atm pressure and 0 °C.

Chemistry
1 answer:
N76 [4]3 years ago
6 0

Answer:

Solution:-

The gas is in the standard temperature and pressure condition i.e. at S.T.P

Therefore,

V

i

​

=22.4dm

3

V

f

​

=?

As given that the expansion is isothermal and reversible

∴ΔU=0

Now from first law of thermodynamics,

ΔU=q+w

∵ΔU=0

∴q=–w

Given that the heat is absorbed.

∴q=1000cal

⇒w=−q=−1000cal

Now,

Work done in a reversible isothermal expansion is given by-

w=−nRTln(

V

i

​

V

f

​

​

)

Given:-

T=0℃=273K

n=1 mol

∴1000=−nRTln(

V

i

​

V

f

​

​

)

⇒1000=−1×2.303×2×273×log(

22.4

V

f

​

​

)

Explanation:

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4 0
4 years ago
Read 2 more answers
How many grams of sodium acetate ( molar mass = 83.06 g/mol ) must be added to 1.00 Liter of a 0.200 M acetic acid solution to m
Pie

<u>Answer:</u> The mass of sodium acetate that must be added is 30.23 grams

<u>Explanation:</u>

To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}

Molarity of acetic acid solution = 0.200 M

Volume of solution = 1 L

Putting values in above equation, we get:

0.200M=\frac{\text{Moles of acetic acid}}{1L}\\\\\text{Moles of acetic acid}=(0.200mol/L\times 1L)=0.200mol

To calculate the pH of acidic buffer, we use the equation given by Henderson Hasselbalch:

pH=pK_a+\log(\frac{[\text{salt}]}{[\text{acid}]})  

pH=pK_a+\log(\frac{[CH_3COONa]}{[CH_3COOH]})

We are given:

pK_a = negative logarithm of acid dissociation constant of acetic acid = 4.74

[CH_3COONa]=?mol  

[CH_3COOH]=0.200mol

pH = 5.00

Putting values in above equation, we get:

5=4.74+\log(\frac{[CH_3COONa]}{0.200})

[CH_3COONa]=0.364mol

To calculate the mass of sodium acetate for given number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Molar mass of sodium acetate = 83.06 g/mol

Moles of sodium acetate = 0.364 moles

Putting values in above equation, we get:

0.364mol=\frac{\text{Mass of sodium acetate}}{83.06g/mol}\\\\\text{Mass of sodium acetate}=(0.364mol\times 83.06g/mol)=30.23g

Hence, the mass of sodium acetate that must be added is 30.23 grams

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Explanation:

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