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NARA [144]
3 years ago
12

10. At 573K, NO2(g) decomposes forming NO and O2. The decomposition reaction is second order in NO2 with a rate constant of 1.1

M-1s-1. If the initial concentration of NO2 is 0.056 M, how long will it take for 75% of the NO2 to decompose
Chemistry
1 answer:
leva [86]3 years ago
6 0

Answer:

48.67 seconds

Explanation:

From;

1/[A] = kt + 1/[A]o

[A] = concentration at time t

t= time taken

k= rate constant

[A]o = initial concentration

Since [A] =[A]o - 0.75[A]o

[A] = 0.056 M - 0.042 M

[A] = 0.014 M

1/0.014 = (1.1t) + 1/0.056

71.4 - 17.86 = 1.1t

53.54 = 1.1t

t= 53.54/1.1

t= 48.67 seconds

Hence,it takes 48.67 seconds to decompose.

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A man heats a balloon in the oven. If the balloon initially has a volume of 0.4 liters and a temperature of 20 degrees celsius,
Airida [17]

Answer:

0.714 liter.

Explanation:

Given:

The balloon initially has a volume of 0.4 liters and a temperature of 20 degrees Celsius.

It is heated to a temperature of 250 degrees Celsius.

Question asked:

What will be the volume of the balloon after he heats it to a temperature of 250 degrees Celsius ?

Solution:

By using:

PV=nRT

Assuming pressure as constant,

V∝ T

Now, let  K is the constant.

V = KT

Let initial volume of balloon , V_{1} = 0.4 liter

1000 liter = 1 meter cube

1 liter = \frac{1}{1000} m^{3} = 10^{-3} m^{3

0.4 liter = 0.4\times10^{-3}=4\times10^{-4} m^{3}

And initial temperature of balloon, T_{1} = 20°C = (273 + 20)K

                                                                          = 293 K

Let the final volume of balloon is V_{2}

And a given, final temperature of balloon, T_{2} is 250°C = (273 + 250)K

                                                                                          = 523 K

Now, V_{1} = KT_{1}

          4\times10^{-4}=K\times293\ (equation\ 1 )

V_{2} = KT_{2}

    =K\times523\ (equation 2)

Dividing equation 1 and 2,

 \frac{4\times10^{-4}}{V_{2} } =\frac{K\times293}{K\times523}

K cancelled by K.

By cross multiplication:

293V_{2} =4\times10^{-4} \times523\\V_{2} =\frac{ 4\times10^{-4} \times523\\}{293} \\          = \frac{2092\times10^{-4}}{293} \\          =7.14\times10^{-4}m^{3}

Now convert it into liter with the help of calculation done above.

7.14\times10^{-4} \times1000\\7.14\times10^{-4} \times10^{3} \\0.714\ liter

Therefore, the volume of the balloon be after he heats it to a temperature of 250 degrees Celsius is 0.714 liter.

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