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We want to calculate the concentrations of all species in a 0.58 M Na 2 SO 3 (sodium sulfite) solution. The ionization constants

NeX [460]

Explanation:

Reaction equation is as follows.

$Na_{2}SO_{3}(s) \rightarrow 2Na^{+}(aq) + SO^{2-}_{3}(aq)$

Here, 1 mole of $Na_{2}SO_{3}$ produces 2 moles of cations.

$[Na^{+}] = 2[Na_{2}SO_{3}] = 2 \times 0.58$

= 1.16 M

$[SO^{2-}_{3}] = [Na_{2}SO_{3}]$ = 0.58 M

The sulphite anion will act as a base and react with $H_{2}O$ to form $HSO^{-}_{3}$ and $OH^{-}$ .

As, $K_{b} = \frac{K_{w}}{K_{a_{2}}}$

= $\frac{10^{-14}}{6.3 \times 10^{-8}}$

= $1.59 \times 10^{-7}$

According to the ICE table for the given reaction,

$SO^{2-}_{3} + H_{2}O \rightleftharpoons HSO^{-}_{3} + OH^{-}$

Initial: 0.58 0 0

Change: -x +x +x

Equilibrium: 0.58 - x x x

So,

$K_{b} = \frac{[HSO^{-}_{3}][OH^{-}]}{[SO^{2-}_{3}]}$

$1.59 \times 10^{-7} = \frac{x^{2}}{0.58 - x}$

$x^{2} = 1.59 \times 10^{-7} \times (0.58 - x)$

x = 0.0003 M

So, x = $[HSO^{-}_{3}] = [OH^{-}]$ = 0.0003 M

$[SO^{2-}_{3}]$ = 0.58 - 0.0003

= 0.579 M

Now, we will use $[HSO^{-}_{3}]$ = 0.0003 M

The reaction will be as follows.

$HSO^{2-}_{3} + H_{2}O \rightleftharpoons H_{2}SO_{3} + OH^{-}$

Initial: 0.0003

Equilibrium: 0.0003 - x x x

$K_{b} = \frac{x^{2}}{0.0003 - x}$

$K_{b} = \frac{K_{w}}{K_{a_{1}}}$

= $\frac{10^{-14}}{1.4 \times 10^{-2}}$

= $7.14 \times 10^{-13}$

Therefore, $7.14 \times 10^{-13} = \frac{x^{2}}{0.0003 - x}$

As, x <<<< 0.0003. So, we can neglect x.

Therefore, $x^{2} = 7.14 \times 10^{-13} \times 0.0003$

= $0.00214 \times 10^{-13}$

x = $0.0146 \times 10^{-6}$

x = $[OH^{-}] = [H_{2}SO_{3}]$ = $1.46 \times 10^{-8}$

$[H^{+}] = \frac{10^{-14}}{[OH^{-}]}$

= $\frac{10^{-14}}{0.0003}$

= $3.33 \times 10^{-11}$ M

Thus, we can conclude that the concentration of spectator ion is $3.33 \times 10^{-11}$ M.

5 0

3 years ago

what is the boiling point of a 0.321 m aqueous solution of NaCl. Enter your rounded answer with 3 decimal places.

Ronch [10]

Answer:

I believe the rounded place is 100.333.

3 0

3 years ago

Read 2 more answers

A 453 g piece of glass at 25.7∘C is left outside on a sunny day. How much heat must the glass absorb from the sun in order to re

Tju [1.3M]

Answer:

Q = 5555.6J

Explanation:

Mass of glass piece, m = 453g

initial temperature = 25.7°C

temperature to be attained = 40.3°C

⇒change in temperature, Δt = 40.3 - 25.7 = 14.6°C

specific heat of glass, s = 0.840J/g°C

Heat absorbed, Q = msΔt

⇒Q = 453×0.840×14.6 = 5555.592J

⇒<u>Q = 5555.6J</u> (rounded to the nearest tenth)

7 0

4 years ago

If you mix cu2+ with? a. nacl, b. nano2, c. h2o , arrange the solutions based on their absorption from highest frequency to lowe

erica [24]

The arrangement of the solutions based on their absorption from highest frequency to lowest frequency :

b. $NaN$ $O_{2}$ > c. $H_{2} O$ > a.NaCl

<h3>What is absorption frequency?</h3>

The frequency of the molecular vibration that led to the absorption is the same as the absorption frequency of a basic IR absorption band.

In a way, an emission spectrum is the opposite of an absorption spectrum.
The discrepancies in the energy levels of each chemical element's orbitals correspond to absorption lines for each chemical element at various particular wavelengths.
Therefore, it is possible to identify the constituents in a gas or liquid using its absorption spectrum.
Absorption spectroscopy is most frequently used to measure infrared, atomic, visible, ultraviolet (UV), and x-ray waves.

Learn more about Absorption frequency here:

brainly.com/question/5032775

#SPJ4

3 0

1 year ago

“What types of friction occur between your bike tires and the ground when you ride over cement, through a puddle, and when you a

Kruka [31]

The right answer is= <span>rolling, fluid, and sliding</span>

4 0

3 years ago